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US 11,697,738 B2Granted
Composition, its preparation method, and the use of the composition in construction application
AssigneeBASF SE
InventorsLei Meng, Sheng Zhong Zhou, Harald Roeckel
Life of this patent
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Abstract
The present invention relates to a curable resin composition. More specifically, the present invention relates to a composition comprising methylene malonate functional reactive resin, to its preparation methods, and to the use of the composition in the construction field.
Claims15
A composition comprising
- (A) at least one methylene malonate monomer having formula (I)
- wherein, R1 and R2 are independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl, C3-C30-cyclolalkyl, C2-C30-heterocyclyl, C2-C30-heterocyclyl-C1-C30-alkyl, C6-C30-aryl, C6-C30-aryl-C1-C30-alkyl, C2-C30-heteroaryl, C2-C30-heteroaryl-C1-C30-alkyl, C1-C30-alkoxy-C1-C30-alkyl, halo-C1-C30-alkyl, and halo-C3-C30-cycloalkyl, each of which radicals is optionally substituted, the heteroatom being selected from N, O and S;
- (B) at least one methylene malonate compound having formula (II):
- wherein, R3 and R4 are independently selected from the group consisting of C1-C30-alkyl, C2-C30-alkenyl, C3-C30-cyclolalkyl, C2-C30-heterocyclyl, C2-C30-heterocyclyl-C1-C30-alkyl, C6-C30-aryl, C6-C30-aryl-C1-C30-alkyl, C2-C30-heteroaryl, C2-C30-heteroaryl-C1-C30-alkyl, C1-C30-alkoxy-C1-C30-alkyl, halo-C1-C30-alkyl, and halo-C3-C30-cyclolalkyl, each of which radicals is optionally substituted, the heteroatom being selected from N, O and S;
- n is an integer from 1 to 20;
- R5, if n=1 is, or if n>1 are independently, selected from the group consisting of C1-C30-alkylene, C2-C30-alkenylene, C2-C30-alkynylene, C6-C30-arylene, C3-C30-cyclolalkylene, C3-C30-cyclolalkenylene, C3-C30-cyclolalkynylene, C2-C30-heterocyclylene, and C2-C30-heteroarylene, each of which radicals is optionally substituted, the heteroatom being selected from N, O and S, wherein R5 is optionally interrupted by a radical selected from N, O and S;
- and
- (C) two or more acidic stabilizers selected from the group consisting of methane sulfonic acid, sulfuric acid, trifluoromethane sulfonic acid, tri-chloroacetic acid, and dichloroacetic acid;
- wherein, the monomer (A) is in an amount of 37 to 75 wt. % and the component (C) is in an amount of from 0.1 to 1000 ppm in each case based on the total weight of the monomer (A) and the compound (B).
6 more elements
Dependencies are inferred from the claim text.