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US 11,695,154 B2Granted
Electrolyte containing siloxane compound and lithium secondary battery including the electrolyte
AssigneesSamsung Electronics Co., Ltd., Samsung SDI Co., Ltd.
InventorsYoonsok Kang, Myongchun Koh, Jihyun Jang, Insun Park, Jinah Seo, Yeonji Chung
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Abstract
An electrolyte and a lithium secondary battery including the same. The electrolyte includes a lithium salt; an organic solvent; and at least one siloxane compound represented by Formula 1 or Formula 2, wherein an amount of the at least one siloxane compound is about 0.05 wt % to about 20 wt % based on a total weight of the electrolyte. In Formulae 1 and 2, group substituents and number indices are as defined in the specification.
Claims20
An electrolyte comprising:
- a lithium salt;
- an organic solvent;
- and
- at least one siloxane compound represented by Formula 1 or Formula 2,
- wherein an amount of the at least one siloxane compound is 0.05 weight percent to 20 weight percent, based on a total weight of the electrolyte
- wherein, in Formulae 1 and 2,
- X1 is hydrogen, a hydroxyl group, or a substituted or unsubstituted C1-C10 alkyl group,
- Y1 is hydrogen or —Si(R3)(R4)(R5),
- n1 is an integer from 1 to 1000,
- n2 is an integer from 1 to 5, and
- R1 to R13 are each independently hydrogen, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C6-C20 aryl group, or a polyalkylene oxide group represented by *—R31—O—(RO)m2—R32, wherein R31 is a substituted or unsubstituted C1-C10 alkylene group, and * represents a point of attachment to Si, RO is an alkylene oxide group, m2 is an integer from 1 to 20, and R32 is hydrogen or a substituted or unsubstituted C1-C10 alkyl group,
- wherein, in Formula 1, X1 is a hydroxyl group or Y1 is hydrogen, and
- in Formula 2, at least one of R6 to R13 is the polyalkylene oxide group.
10 more elements
Dependencies are inferred from the claim text.