Method for making fluorocarbon free emulsions without using traditional surfactants/emulsifiers by emulsifying alkoxysilanes or other non-water soluble hydrophobizing agents using amino functional siloxanes and the uses thereof

An emulsified liquid composition comprising

• a) one or more amino functional organosiloxane of the formula I
• wherein, Ra, Rb, Rc and Rd, which may be identical or different, denote a hydrogen atom, a phenyl, a benzyl, a C1-C32 alkyl group, a C1-C4 alkoxy group;
• m and n are integers dependent on the degree of polymerization and whose sum is between 1 and 2000 and/or weight-average molecular mass of the compound is between 5000 and 500000 and the amino-functional organic group RN is illustrated by groups having the formula
• —R3NHR4, —R3NR42, or —R3NHR3NHR4, wherein each R3 is independently a divalent hydrocarbon group having at least 2 carbon atoms, and R4 is hydrogen or an alkyl group, and wherein said one or more amino functional organosiloxane is protonated and has a nitrogen content of 0.05 weight % N—0.4weight % N;
• b) one or more hydrolysable alkylsilanes of the formula II
• (R′O)mSi(R″)n Formula II,
• wherein
• R″=C3-C30 alkyl
• and the sum of the m+n must be 4, while m≥1;
• c) an acid;
• d) water;
• e) a defoamer;
• f) a coalescent agent;
• and optionally one or more of a preservative, co-emulsifier, catalyst, rheology modifier, fatty acid, oil and/or wax.