Fluoro (poly) ether group-containing silane compound
AssigneeDaikin Industries, Ltd.
InventorsHisashi Mitsuhashi, Takashi Nomura, Masato Naitou, Shinya Takano, Yuusuke Watanabe, Kaori Ozawa, Peter Hupfield
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Abstract
A fluoro(poly)ether group-containing silane compound represented by any of the formulae (A1), (A2), (B1), (B2), (C1), or (C2). In the formulae, PFPE is each independently at each occurrence a group represented by the formula: —(OC3F6)d—, wherein the repeating unit OC3F6 of the formula includes a branched structure, and d is an integer of 2 or more and 200 or less. The symbols are as defined in the description.
Claims11
A fluoro(poly)ether group-containing silane compound represented by any of the formulae (B1), and (B2):
- Rf-PFPE—X3—SiRak1 (B1)
- Rak1Si—X3—PFPE—X3—SiRak1 (B2)
- wherein:
- Rf each independently at each occurrence represents an alkyl group having 1 to 16 carbon atoms which is optionally substituted by one or more fluorine atoms;
- -PFPE-X3— represents —(OC3F6)d—(OCF(CF3))—X10—CONH—X11—, or —(OC3F6)d—(OCF(CF3))—X10—(OR35)n4—X11—;
- —X3-PFPE-X3— represents —X11—NHCO—X10—(OC3F6)d—(OCF(CF3))—X10—CONH—X11—, or —X11—(R35O)n4—X10—(OC3F6)d—(OCF(CF3))—X10—(OR35)n4—X11—;
- wherein the repeating unit OC3F6 of the formula has a branched structure, and d is an integer of 2 or more and 200 or less;
- X10 is each independently at each occurrence a single bond or R36;
- R36 is a C1-20 alkylene group which is optionally substituted by one or more fluorine atoms;
- X11 is each independently at each occurrence a C1-20 alkylene group;
- R35 is each independently at each occurrence a C1-6 unsubstituted alkylene group;
- n4 is each independently at each occurrence an integer of 1 to 5;
- Ra each independently at each occurrence represents —Z3—SiR723;
- Z3 each independently at each occurrence represents C1-6 alkylene group;
- R72 each independently at each occurrence represents a hydroxyl group or a hydrolyzable group;
- k1 is 3.
A compound represented by the formula (c1-3) or (c2-3):
- wherein:
- Rf each independently at each occurrence represents an alkyl group having 1 to 16 carbon atoms which is optionally substituted by one or more fluorine atoms;
- -PFPE-X10— is represented by —(OCF(CF3)CF2)d—(OCF(CF3))—, or —(OCF(CF3)CF2)d—(OCF(CF3))—R36—;
- —X10-PFPE-X10— is represented by —(OCF(CF3)CF2)d—(OCF(CF3))—, or —R36—(OCF(CF3)CF2)d—(OCF(CF3))—R36—;
- d is an integer of 2 or more and 200 or less;
- R36 is a C1-20 alkylene group which is optionally substituted by one or more fluorine atoms;
- X11 is each independently at each occurrence a C1-20 alkylene group which is optionally substituted by one or more fluorine atoms;
- and
- Y11 is each independently at each occurrence a single bond or C1-4 alkylene group.
Dependencies are inferred from the claim text.