Olefin oligomerization catalyst and method for producing olefin oligomer in the presence of the same catalyst
AssigneeMitsui Chemicals, Inc.
InventorsSeiichi Ishii, Shinichiro Ichikawa, Terunori Fujita
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Abstract
A method for producing an olefin oligomer is disclosed, in which an olefin oligomerization reaction is performed in the presence of an olefin oligomerization catalyst comprising (A) a chromium compound, (B) an amine compound of the general formula (1): (R1 to R4 represent a group such as a hydrocarbon group, Y represents a structure represented by —CR5R6—, R5 and R6 represent a group such as a hydrogen atom, and Z represents an integer of 1 to 10), and (C) a compound such as an organometal compound; and the olefin oligomerization catalyst.
Claims12
A method for producing an olefin oligomer, comprising performing an olefin oligomerization reaction in the presence of an olefin oligomerization catalyst containing the following components (A) to (C):
- (A) a chromium compound,
- (B) an amine compound represented by the following general formula (1):
- (in the general formula (1), R1 to R4 may be the same or different from each other, and each represents a hydrogen atom, a halogen atom, a hydrocarbon group that does not contain a nitrogen-containing group or a phosphorus-containing group, a heterocyclic compound residue, an oxygen-containing group, a boron-containing group, an aluminum-containing group, a sulfur-containing group, a silicon-containing group, a germanium-containing group or a tin-containing group, and two or more thereof may be connected each other,
- Y represents a carbon atom having substituents R5 and R6 (a structure represented by —CR5R6—), R5 and R6 may be the same or different from each other, and each represents a hydrogen atom, a halogen atom, a hydrocarbon group, a heterocyclic compound residue, an oxygen-containing group, a nitrogen-containing group, a boron-containing group, an aluminum-containing group, a sulfur-containing group, a phosphorus-containing group, a silicon-containing group, a germanium-containing group or a tin-containing group, and R5 and R6 may be connected each other, and each of R5 and R6 may be connected to any one of R1 to R4,
- Z represents an integer of 1 to 10) and
- (C) at least one compound selected from the group consisting of
- (C-1) an organometal compound,
- (C-2) an organoaluminumoxy compound and
- (C-3) a compound reacting with a transition metal compound to form an ion pair.
Dependencies are inferred from the claim text.