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US 11,680,152 B2Granted
Recyclable polymers from environmentally benign building blocks
AssigneeTriad National Security, LLC
InventorsAndrew D. Sutton, Christopher David Roland, Cameron M. Moore
Life of this patent
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Abstract
Disclosed herein are embodiments of a method for making recyclable polymers and a method for decomposing the polymers back to the monomers which can then be reused. The polymer are stable to aqueous and/or acid conditions and may have a formula II The method to decompose the polymer back to the monomers may comprise heating the polymer in a protic organic solvent.
Claims16
A method, comprising:
- forming a first mixture comprising a protic organic solvent, a co-solvent, and a first polymer according to Formula II
- heating the first mixture to a temperature of from 40° C. to 75° C. for 3 days;
- isolating a recycled monomer compound according to Formula I from the first mixture
- forming a second mixture comprising the recycled monomer compound according to Formula I, a carbonyl compound according to Formula III, and a base;
- heating the second mixture to a first temperature of from 80° C. to 150° C. for a first time period;
- heating the second mixture to a second temperature of from greater than 150° C. to 300° C. for a second time period;
- and
- isolating a second polymer according to Formula II
- wherein
- R1 is alkyl or OH;
- R2 is aliphatic substituted with OH;
- each R4 independently is H, C1-6alkyl, or phenyl;
- each of Ra and Rb independently is Cl, OCCl3, OPh, or OC1-6alkyl;
- L is C1-6alkyl or C2-6alkenyl;
- each n independently is 2 to 500;
- x is 1, 2, 3, 4, 5 or 6;
- and
- y is 1 or 2.
15 more elements
Dependencies are inferred from the claim text.