Reactor and process for producing alkyl methacrylates
AssigneeRohm Co., Ltd.
InventorsSteffen Krill, Andreas Rühling, Belaid Ait Aissa
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Abstract
A process produces methyl methacrylate by direct oxidative esterification of methacrolein. Methyl methacrylate is used in large amounts for producing polymers and copolymers with other polymerizable compounds. An optimized workup of the reactor discharge from the oxidative esterification of methacrolein allows for co-discharged fine catalyst particles to be very efficiently separated and optionally removed or recycled. In addition, this process can reduce the formation of byproducts in extended continuous operation compared to known variant. A reactor system contains stirrer configurations which allow virtually abrasion-free operation and thus a catalyst on-stream time of several years.
Claims20
A process for producing alkyl methacrylates, comprising:
- reacting methacrolein with an alkyl alcohol in the presence of an oxygen-containing gas and a particulate, pulverulent catalyst in a liquid phase, in a reaction mixture in a reactor, to obtain an alkyl methacrylate;
- wherein the reactor comprises a zone A, at least one zone B-1, at least one zone B-2, a zone B-3, and at least one zone C, and
- wherein
- zone A represents a primary reaction zone and is provided with at least one stirring means for intensive commixing of gaseous, liquid, and solid phases in zone A,
- the at least one zone B-1 is provided with internals for flow calming which very largely prevent entry of the gaseous phase into subsequent zones of the at least one zone B-2, zone B-3, and the at least one zone C,
- zone B-3 contains the reaction mixture which has been very largely freed of the gaseous phase and is connected to the at least one zone C,
- the at least one zone C comprises a continuously classifying sedimentation apparatus, wherein an average vertical flow in zone A and the at least one zone C is upwards, and an average vertical flow in the at least one zone B-1, the at least one zone B-2, and zone B-3 is downwards, and
- an energy input for suspension of the catalyst by the at least one stirring means is limited to not more than 3 kilowatts per cubic meter of the reaction mixture.
Dependencies are inferred from the claim text.