Inorganic paint pigment with plasmonic aluminum reflector layers and related methods
AssigneeUniversity of Central Florida Research Foundation, Inc.
InventorsDebashis Chanda, Daniel Franklin, Pablo Manuel Cencillo Abad
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Abstract
An inorganic paint pigment may include a fluid matrix, and paint flakes carried within the fluid matrix. Each paint flake may include a common aluminum layer having a first major surface and a second major surface opposing the first major surface, a first plasmonic aluminum reflector layer carried by the first major surface, and a second plasmonic aluminum reflector layer carried by the second major surface.
Claims22
An inorganic paint pigment comprising:
- a fluid matrix;
- and
- a plurality of paint flakes carried within the fluid matrix;
- each paint flake comprising
- a common aluminum layer having a first major surface and a second major surface opposing the first major surface,
- a first plasmonic aluminum reflector layer carried by the first major surface, and
- a second plasmonic aluminum reflector layer carried by the second major surface;
- each of the first plasmonic aluminum reflector layer and the second plasmonic aluminum reflector layer comprising
- an oxide layer over the common aluminum layer, and
- a layer of self-assembled aluminum particles over the oxide layer and having hybridized individual plasmonic modes to provide angle independent color, a gap between the common aluminum layer and the layer of self-assembled aluminum particles being less than 10 nm.
An inorganic paint pigment comprising:
- a fluid matrix;
- and
- a plurality of paint flakes carried within the fluid matrix;
- each paint flake comprising
- a common aluminum mirror layer having a first major surface and a second major surface opposing the first major surface,
- a first plasmonic aluminum reflector layer carried by the first major surface, and
- a second plasmonic aluminum reflector layer carried by the second major surface,
- each of the first plasmonic aluminum reflector layer and the second plasmonic aluminum reflector layer comprising
- an oxide layer over the common aluminum mirror layer, and
- a layer of self-assembled aluminum particles over the oxide layer and having hybridized individual plasmonic modes to provide angle independent color, a gap between the common aluminum mirror layer and the layer of self-assembled aluminum particles being less than 10 nm, a wavelength of the angle independent color being based upon a diameter of the self-assembled aluminum particles.
A method for making an inorganic paint pigment comprising:
- forming a plasmonic aluminum reflector stack on a sacrificial polymer layer;
- and
- releasing the plasmonic aluminum reflector stack via a sonication step into a solvent and generating a plurality of paint flakes from the plasmonic aluminum reflector stack, each paint flake comprising
- a common aluminum layer having a first major surface and a second major surface opposing the first major surface,
- a first plasmonic aluminum reflector layer carried by the first major surface, and
- a second plasmonic aluminum reflector layer carried by the second major surface.
Dependencies are inferred from the claim text.