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US 11,655,203 B2Granted
Nitration
AssigneeETH Zurich
InventorsDmitry Katayev, Kun Zhang, Roxan Calvo
Life of this patent
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Abstract
A process for preparing a nitrated compound, including the step of reacting a compound (A) including at least one substituted or unsubstituted aromatic or heteroaromatic ring, wherein the heteroaromatic ring includes at least one heteroatom selected from the group consisting of oxygen, sulfur, phosphor, selenium and nitrogen, with a compound of formula (I) wherein Y is selected from the group consisting of hydrogen and nitro.
Claims18
A process for preparing a nitrated compound, comprising the step of
- reacting a compound (A) having at least one aromatic or heteroaromatic ring optionally substituted by one or more organic residues R,
- wherein the organic residue R is selected from the group consisting of fluoro, chloro, bromo, iodo, amino, cyano, hydroxy, nitro, C1-12 alkyl, C2-15 alkenyl, C2-15 alkynyl, C3-15 cycloalkyl, C3-15 cycloalkenyl, cycloalkynyl, C3-5 alkylene, C3-5 cycloalkylene, C3-5 alkenylene, C3-5 alkynylene, halo-C1-6 alkyl, hydroxy-C1-6 alkyl, halo-C3-15 cycloalkyl, C1-10 alkoxy, C3-5 cycloalkoxy, alkylenedioxy, C1-6 acyl, C3-6 cycloacyl, C1-6 acyloxy, C3-6 cycloacyloxy, arylalkyl, heteroarylalkyl, aryl, and heteroaryl group, and where the organic residue R may optionally form an annealed ring system with other rings selected from cycloalkyl, aryl, and heteroaryl rings, and
- wherein the heteroaromatic ring includes at least one heteroatom selected from the group consisting of oxygen, sulfur, phosphor, selenium and nitrogen,
- with a compound of formula (I)
- wherein Y is selected from the group consisting of hydrogen and nitro.
2 more elements
A method comprising applying a compound of formula (I)
- wherein Y is selected from the group consisting of hydrogen and nitro,
- as nitrating agent of a compound (A) comprising an aromatic or heteroaromatic ring.
Dependencies are inferred from the claim text.