Back to results
US 11,643,373 B1Granted
Integrated reactor for ionic liquid alkylation using bio-ethylene feedstock
AssigneeChevron U.S.A. Inc.
InventorsHuping Luo, Hye-Kyung Cho Timken, Bong-Kyu Chang
Life of this patent
Estimating the term…
Abstract
An alkylation process is described. The process involves alkylation of isobutane and ethylene in a loop reactor using an ionic liquid catalyst as a continuous phase. The alkylate typically has a research octane number of at least about 93, and the olefin conversion is typically at least about 95%.
Claims15
A process for the catalytic alkylation of an olefin with an isoparaffin in a loop reactor system, the process comprising:
- (a) introducing a bio-ethylene feed and an isobutane feed into a loop reactor system comprising at least one loop reactor;
- (b) supplying an ionic liquid catalyst to the reactor system, wherein the ionic liquid catalyst comprises an organic cation and a halometallate anion, and the ionic liquid is present in an amount of at least 35 vol. % of a total volume of fluid in the loop reactor system;
- (c) circulating the ethylene feed and isobutane feed through the loop reactor in the presence of the ionic liquid catalyst under reaction conditions effective for reaction between the ethylene and the isobutane to produce an alkylate having a research octane number (RON) of 93 or more;
- wherein the reaction conditions include a temperature of from 30° C. to 100° C., a pressure of from 300 psig to 700 psig (2068 kPa to 4826 kPa), and an overall paraffin to olefin molar ratio of from 2 to 20;
- and
- wherein fluid circulating through the loop reactor system comprises a continuous phase comprising the ionic liquid and a dispersed phase comprising hydrocarbons.
3 more elements
Dependencies are inferred from the claim text.