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US 11,639,403 B2Granted
Polymer, composite positive active material including the same, and lithium secondary battery including electrode including the positive active material
AssigneesSamsung Electronics Co., Ltd., Waseda University
InventorsWonsung Choi, Hiroyuki Nishide, Seokgwang Doo, Kenichi Oyaizu
Life of this patent
Estimating the term…
Abstract
A polymer includes a repeating unit represented by at least one of Formula 1a or Formula 1b: wherein, in Formulae 1a or 1b, CY1 is a group represented by at least one of Formula 1-2 or Formula 1-4, CY2 is a group represented by Formula 1-3, and L1, L2, a1, and a2 are defined the same as in the specification, and in Formulae 1-2, Formula 1-3, or 1-4, X, Y, R1, R2, R11 to R14, b1, b2, R21, R22, b21, b22, Z1, Z2, c1, and c2 are defined the same as in the specification.
Claims20
A polymer comprising:
- a repeating unit represented by at least one of Formula 1a or Formula 1b
- wherein, in Formulae 1a and 1b,
- CY1 is a group represented by at least one of Formula 1-2 or Formula 1-4,
- CY2 is a group represented by Formula 1-3,
- L1 and L2 are each independently a single bond, a substituted or unsubstituted C1-C20 alkylene group, a substituted or unsubstituted C2-C20 alkenylene group, or a substituted or unsubstituted C2-C20 alkynylene group, and
- a1 and a2 are each independently an integer from 1 to 5, and two or more L1 are the same or different from one another when a1 is 2 or greater, and two or more L2 are the same or different from each other when a2 is 2 or greater,
- wherein, in Formulae 1-2 and 1-3,
- X and Y are each independently O or S,
- R1, R2, and R11 to R14 are each independently hydrogen, deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C1-C60 alkyl group, a substituted or unsubstituted C2-C60 alkenyl group, a substituted or unsubstituted C2-C60 alkynyl group, a substituted or unsubstituted C1-C60 alkoxy group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C1-C10 heterocycloalkyl group, a substituted or unsubstituted C3-C10 cycloalkenyl group, a substituted or unsubstituted C1-C10 heterocycloalkenyl group, a substituted or unsubstituted C6-C60 aryl group, a substituted or unsubstituted C6-C60 aryloxy group, a substituted or unsubstituted C6-C60 arylthio group, a substituted or unsubstituted C1-C60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, or a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group,
- b1 and b2 are each independently an integer from 1 to 3, and two or more R1 are the same or different from one another when b1 is 2 or greater, and two or more R2 are the same or different from one another when b2 is 2 or greater, and
- in Formula 1-4,
- R21 and R22 are each independently hydrogen, deuterium, —F, —Cl, —Br, —I, a hydroxyl group, a cyano group, a nitro group, an amino group, an amidino group, a hydrazine group, a hydrazone group, a carboxylic acid group or a salt thereof, a sulfonic acid group or a salt thereof, a phosphoric acid group or a salt thereof, a substituted or unsubstituted C1-C60 alkyl group, a substituted or unsubstituted C2-C60 alkenyl group, a substituted or unsubstituted C2-C60 alkynyl group, a substituted or unsubstituted C1-C60 alkoxy group, a substituted or unsubstituted C3-C10 cycloalkyl group, a substituted or unsubstituted C1-C10 heterocycloalkyl group, a substituted or unsubstituted C3-C10 cycloalkenyl group, a substituted or unsubstituted C1-C10 heterocycloalkenyl group, a substituted or unsubstituted C6-C60 aryl group, a substituted or unsubstituted C6-C60 aryloxy group, a substituted or unsubstituted C6-C60 arylthio group, a substituted or unsubstituted C1-C60 heteroaryl group, a substituted or unsubstituted monovalent non-aromatic condensed polycyclic group, or a substituted or unsubstituted monovalent non-aromatic condensed heteropolycyclic group,
- b21 and b22 are each independently an integer from 0 to 3, and two or more R21 are the same or different from one another when b21 is 2 or greater, and two or more R22 are the same or different from one another when b22 is 2 or greater,
- Z1 and Z2 are each independently an electron withdrawing group,
- C1 and c2 are each independently an integer of 1 to 4,
- the sum of b21and c1 is 4,
- the sum of b22 and c2 is 4,
- is a binding site to L1 in Formulae 1a and 1b, and
- is a binding site to L2 in Formula 1b.
16 more elements
Dependencies are inferred from the claim text.