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US 11,639,320 B1Granted
Process for the production of renewable distillate-range hydrocarbons
AssigneeChevron U.S.A. Inc.
InventorsBong Kyu Chang, Hye-Kyung Cho Timken, Michelle K. Young
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Abstract
A process for producing renewable distillate-range hydrocarbons is provided. The process includes dehydrating a renewable C2-C6 alcohol feedstock to produce an olefin, oligomerizing the olefin the presence of a halometallate ionic liquid catalyst to produce an oligomer product and hydrogenating the oligomer product or fractions thereof to produce saturated distillate-range hydrocarbons.
Claims20
A process for producing distillate-range hydrocarbons, the process comprising:
- (a) dehydrating bio-alcohols in a fermentation stream comprising isobutanol to form an olefin stream and a water stream wherein the dehydration process is conducted at selected process conditions sufficient to achieve conversion of the bio-alcohols that is 95% or more and wherein an amount of oxygenates in the olefin stream is less than 1 wt. %;
- (b) separating the olefin stream from the water stream;
- (c) contacting the olefin stream with a halometallate ionic liquid catalyst, the halometallate ionic liquid catalyst comprising an organic cation and a halometallate anion, in an oligomerization reactor under oligomerization conditions to form a mixture comprising the halometallate ionic liquid catalyst and an oligomer product, wherein at least 50 wt. % of the oligomer product has boiling point distribution of from 150° C. to 400° C.;
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- (d) separating the oligomer product from the halometallate ionic liquid catalyst.
2 more elements
Dependencies are inferred from the claim text.