Enhanced tail gas treatment of sulfur recovery unit with steam swept membranes
AssigneeSaudi Arabian Oil Company
InventorsFeras Hamad, Sebastien A. Duval, Milind M. Vaidya, Ahmad A. Bahamdan, Faisal D. Al-Otaibi
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Abstract
This invention relates to a system and method for improving sulfur recovery from a Claus unit. More specifically, this invention provides a steam swept membrane tail gas treatment system and method for treating acid gas streams and minimizing sulfur dioxide emissions therefrom.
Claims19
A method for removing sulfur-containing compounds from a sulfur recovery unit (SRU) tail gas stream, the method comprising the steps of:
- a) introducing the SRU tail gas stream produced by the SRU to a sulfur-converting unit to produce a membrane feed;
- b) introducing the membrane feed to a sulfur membrane unit, the sulfur membrane unit comprising an acid gas-selective membrane, wherein the membrane feed comprises sulfur-containing compounds;
- c) allowing the membrane feed to contact a feed side of the acid gas-selective membrane such that sulfur-containing compounds permeate through the membrane to a permeate side;
- d) supplying a steam feed to the permeate side of the acid gas-selective membrane to produce a sulfur concentrated stream, wherein the sulfur concentrated stream comprises sulfur-containing compounds, and wherein the heat used to produce the steam feed is sourced from the SRU boiler;
- and
- e) collecting the retentate gases that fail to permeate through the membrane to produce a sulfur lean stream retentate, wherein the sulfur lean stream retentate comprises retentate gases.
An apparatus to remove sulfur-containing compounds from a sulfur recovery unit (SRU) tail gas stream, the apparatus comprising:
- a) a sulfur-converting unit configured to produce a membrane feed;
- and
- b) a membrane unit fluidly connected to the converting unit, the membrane unit comprising an acid gas-selective membrane, wherein the membrane feed contacts a feed side of the acid gas-selective membrane such that the sulfur-containing compounds present in the membrane feed permeate through the acid gas-selective membrane to a permeate side, wherein the permeate side is swept with steam forming a sulfur rich stream, and wherein the heat used to produce the steam is sourced from the SRU boiler.
Dependencies are inferred from the claim text.