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US 11,635,685 B2Granted
Resist composition and patterning process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsJun Hatakeyama, Takayuki Fujiwara, Tomomi Watanabe
Life of this patent
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Abstract
A resist composition comprising a base polymer and an acid generator containing a sulfonium or iodonium salt of iodized benzamide group-containing fluorinated sulfonic acid offers a high sensitivity, minimal LWR and improved CDU independent of whether it is of positive or negative tone.
Claims16
A resist composition comprising a base polymer and an acid generator containing a sulfonium salt having the formula (A-1) or iodonium salt having the formula (A-2):
- wherein m is an integer of 1 to 5, n is an integer of 0 to 3, m+n is 1 to 5, p is an integer of 1 to 3,
- L1 is a single bond or C1-C20 divalent linking group when p=1, or a C1-C20 tri- or tetravalent linking group when p=2 or 3, the linking group optionally containing oxygen, sulfur or nitrogen,
- Rf1 to Rf4 are each independently hydrogen, fluorine or trifluoromethyl, at least one of Rf1 to Rf4 being fluorine or trifluoromethyl, Rf1 and Rf2, taken together, may form a carbonyl group,
- R1 is hydroxyl, carboxyl, nitro, cyano, fluorine, chlorine, bromine, amino, or a C1-C20 saturated hydrocarbyl, C1-C20 saturated hydrocarbyloxy, C2-C20 saturated hydrocarbyloxycarbonyl, C2-C20 saturated hydrocarbylcarbonyloxy or C1-C4 saturated hydrocarbylsulfonyloxy group, which may contain fluorine, chlorine, bromine, hydroxyl, amino or ether bond, or —NR1A—C(═O)—R1B or —NR1A—C(═O)—O—R1B, R1A is hydrogen or a C1-C6 saturated hydrocarbyl group which may contain halogen, hydroxyl, C1-C6 saturated hydrocarbyloxy, C2-C6 saturated hydrocarbylcarbonyl or C2-C6 saturated hydrocarbylcarbonyloxy moiety, R1B is a C1-C16 aliphatic hydrocarbyl group or C6-C12 aryl group, which may contain halogen, hydroxyl, C1-C6 saturated hydrocarbyloxy, C2-C6 saturated hydrocarbylcarbonyl or C2-C6 saturated hydrocarbylcarbonyloxy moiety,
- R2 is hydrogen or C1-C4 alkyl, R2 and L1 may bond together to form a ring with the nitrogen atom to which they are attached,
- R3, R4, R5, R6, and R7 are each independently a C1-C20 hydrocarbyl group which may contain a heteroatom, R3 and R4 may bond together to form a ring with the sulfur atom to which they are attached.
3 more elements
Dependencies are inferred from the claim text.