Super absorbent polymer and method for producing same
AssigneeLG Chem, Ltd.
InventorsTae Bin Ahn, Dong Hyun Kim, Yeon Soo Kim, Hyun Sup Lee, Chang Sun Han, Myung Han Lee
Life of this patent
Estimating the term…
Abstract
The super absorbent polymer comprises: a base polymer powder including a first crosslinked polymer of a water-soluble ethylenically unsaturated monomer having at least partially neutralized acidic groups; and a surface crosslinked layer formed on the base polymer powder and including a second crosslinked polymer in which the first crosslinked polymer is further crosslinked via a surface crosslinking agent, wherein the super absorbent polymer has: a fixed height absorption (FHA) of 22.5 g/g to 29 g/g, a saline flow conductivity (SFC) of 35 (·10−7 cm3·s/g) or more, and T-20 of 180 seconds or less.
Claims10
A super absorbent polymer comprising:
- a base polymer powder including a first crosslinked polymer of a water-soluble ethylenically unsaturated monomer having at least partially neutralized acidic groups;
- and
- a surface crosslinked layer formed on the base polymer powder and including a second crosslinked polymer in which the first crosslinked polymer is further crosslinked via a surface crosslinking agent,
- wherein the super absorbent polymer has the following features:
- a fixed height absorption (FHA) (20 cm) for a physiological saline solution (0.9 wt % aqueous sodium chloride solution) of 22.5 g/g to 29 g/g,
- a saline flow conductivity (SFC) for a physiological saline solution (0.685 wt % aqueous sodium chloride solution) of 35 (·10−7 cm3·s/g) or more, and
- T-20 of 180 seconds or less which indicates the time required for absorbing 1 g of the super absorbent polymer to 20 g of aqueous solution of 0.9 wt % sodium chloride and 0.01 wt % alcohol ethoxylate having 12 to 14 carbon atoms under pressure of 0.3 psi,
- wherein the first crosslinked polymer includes a polymer in which the water-soluble ethylenically unsaturated monomer is crosslinked in the presence of an internal crosslinking agent,
- the internal crosslinking agent includes a polyolpoly(meth)acrylate-based first internal crosslinking agent, and an allyl(meth)acrylate-based second internal crosslinking agent,
- the polyolpoly(meth)acrylate-based first internal crosslinking agent is included in an amount of 0.4 to 1 part, and the allyl(meth)acrylate-based second internal crosslinking agent is included in an amount of 0.008 to 0.5 parts, by weight based on 100 parts by weight of a monomer composition including the internal crosslinking agent and the water-soluble ethylenically unsaturated monomer, and
- the allyl(meth)acrylate-based second internal crosslinking agent is allyl acrylate or allyl (meth)acrylate.
A super absorbent polymer comprising:
- a base polymer powder including a first crosslinked polymer of a water-soluble ethylenically unsaturated monomer having at least partially neutralized acidic groups;
- and
- a surface crosslinked layer formed on the base polymer powder and including a second crosslinked polymer in which the first crosslinked polymer is further crosslinked via a surface crosslinking agent,
- wherein the super absorbent polymer has the following features:
- a fixed height absorption (FHA) (20 cm) for a physiological saline solution (0.9 wt % aqueous sodium chloride solution) of 22.5 g/g to 29 g/g,
- a centrifuge retention capacity (CRC) for a physiological saline solution (0.9 wt % aqueous sodium chloride solution) for 30 minutes of 26 g/g to 34 g/g,
- a saline flow conductivity (SFC) for a physiological saline solution (0.685 wt % aqueous sodium chloride solution) of 35 (·10−7 cm3·s/g) or more, and
- a free swell rate (FSR) of 0.25 g/g/s to 0.40 g/g/s when 1 g of the super absorbent polymer absorbs 20 g of a 0.9 wt % aqueous sodium chloride solution,
- wherein the first crosslinked polymer includes a polymer in which the water-soluble ethylenically unsaturated monomer is crosslinked in the presence of an internal crosslinking agent,
- the internal crosslinking agent includes a polyolpoly(meth)acrylate-based first internal crosslinking agent, and an allyl(meth)acrylate-based second internal crosslinking agent,
- the polyolpoly(meth)acrylate-based first internal crosslinking agent is included in an amount of 0.4 to 1 parts, and the allyl(meth)acrylate-based second internal crosslinking agent is included in an amount of 0.008 to 0.5 parts, by weight based on 100 parts by weight of a monomer composition including the internal crosslinking agent and the water-soluble ethylenically unsaturated monomer, and
- the allyl(meth)acrylate-based second internal crosslinking agent is allyl acrylate or allyl (meth)acrylate.
Dependencies are inferred from the claim text.