Polymeric polymerization initiator and method for producing polymeric polymerization initiator
AssigneeShin-Etsu Chemical Co., Ltd.
InventorRyunosuke Hata
Life of this patent
Estimating the term…
Abstract
A polymeric polymerization initiator represented by the following formula (I). M1aM2bD1cD2dT1eT2fQg (I) M1=R13SiO1/2 M2=R12R2SiO1/2 D1=R12SiO2/2 D2=R1R2SiO2/2 T1=R1SiO3/2 T2=R2SiO3/2 Q=SiO4/2 [R1 represents a hydrogen atom, a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group. R2 represents a group having a ketene silyl acetal structure represented by the following formula (II). (A represents a single bond or a divalent organic group, R3 represents a hydrogen atom or a substituted or unsubstituted alkyl group, and R4 represents a substituted or unsubstituted alkyl group.) “a”, “b”, “c”, “d”, “e”, “f”, and “g” represent 0 or a positive integer where b+d+f≥1. An order of bonding of siloxane units is optionally determined.]
Claims2
A polymeric polymerization initiator represented by the following general formula (I):
- M1aM2bD1cD2dT1eT2fQg (I)
- M1=R13SiO1/2
- M2=R12R2SiO1/2
- D1=R12SiO2/2
- D2=R1R2SiO2/2
- T1=R1SiO3/2
- T2=R2SiO3/2
- Q=SiO4/2
- wherein in the general formula (I),
- R1 each independently represents a hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 22 carbon atoms;
- R2 represents a group having a ketene silyl acetal structure represented by the following general formula (II):
- wherein in the general formula (II),
- A represents a single bond or a divalent organic group,
- R3 each independently represents a hydrogen atom or a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms, and
- R4 each independently represents a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms,
- “a”, “c”, “d”, “e”, “f”, and “g” represent 0 or a positive integer and “b” represents 0 where b+d+f≥1;
- the polymerization initiator represented by the general formula (I) has a number-average molecular weight of 2,000 to 1,000,000 g/mol;
- and
- an order of bonding of siloxane units represented by M1, D1, M2, D2, T1, T2, and Q is optionally determined.
Dependencies are inferred from the claim text.