A connecting structure for a drill collar of a logging while drilling instrument, comprising a male connecting joint and a female connecting joint matched with each other, the male connecting joint and the female connecting joint being rotatable relative to each other, electrical passages being respectively arranged in the male connecting joint and the female connecting joint, one of the male connecting joint and the female connecting joint being provided with a multi-core coaxial electrical male connector connected with the corresponding electrical passage, the other being correspondingly provided with a multi-core coaxial electrical female connector connected with the corresponding electrical passage, wherein when the male connecting joint is coaxially nested in the female connecting joint, the multi-core coaxial electrical male connector is inserted into and fitted to the multi-core coaxial electrical female connector, so that the male connecting joint and the female connecting joint are electrically connected.