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US 11,618,804 B2Granted
Polymer and polymer separator comprising same
AssigneeLG Chem, Ltd.
InventorsJinhee Lee, Byungguk Kim, Hyungsam Choi, Yunah Yu
Life of this patent
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Abstract
A polymer including a hydrophilic block and a hydrophobic block, wherein the hydrophilic block includes a unit derived from a compound represented by Chemical Formula 1, and the hydrophobic block includes a unit derived from a fluorine-containing compound, a polymer separator including the same, and a membrane electrode assembly, a fuel cell and a redox flow battery including the same.
Claims12
A polymer comprising:
- a hydrophilic block;
- and
- a hydrophobic block,
- wherein the hydrophilic block includes a repeating unit represented by the following Chemical Formula 4-1;
- and
- the hydrophobic block includes a repeating unit represented by the following Chemical Formula 5-1:
- in Chemical Formula 4-1 and Chemical Formula 5-1
- x1, a and a′ are, as a repetition number of units in the parentheses, an integer of 1 to 1,000, and a:a′ is from 1,000:1 to 1:1,000;
- L11 is —S—;
- A′ is —O(CF2)mSO3H, or —O(CF2)mSO3−M+;
- m is an integer of 2 to 6, and M is a group 1 element;
- R16 and R17 are the same as or different from each other, and each independently is a halogen group;
- n′ is an integer of 2 to 10, and when n′ is an integer of 2 or greater, structures in the parentheses are the same as or different from each other;
- X11 is a direct bond;
- —C(Z11)(Z12)-;
- —O—;
- —S—;
- —SO2-;
- —CO—;
- or —Si(Z11)(Z12)-,
- Z11 and Z12 are the same as or different from each other, and each independently is hydrogen;
- deuterium;
- a halogen group;
- a substituted or unsubstituted alkyl group;
- or a substituted or unsubstituted aryl group;
- and
- T11 and T12 are the same as or different from each other, and each independently is hydrogen;
- deuterium;
- a halogen group;
- a nitrile group;
- a nitro group;
- a hydroxyl group;
- a substituted or unsubstituted alkyl group;
- a substituted or unsubstituted cycloalkyl group;
- a substituted or unsubstituted alkoxy group;
- a substituted or unsubstituted alkenyl group;
- a substituted or unsubstituted silyl group;
- a substituted or unsubstituted amine group;
- a substituted or unsubstituted aryl group;
- or a substituted or unsubstituted heteroaryl group, t11 and t12 are an integer of 0 to 4, and when t11 and t12 are an integer of 2 or greater, substituents in the parentheses are the same as or different from each other;
- and
- x2, b and b′ are, as a repetition number of units in the parentheses, an integer of 1 to 1,000, and b:b′ is from 1,000:1 to 1:1,000;
- X12 is a direct bond;
- —C(Z13)(Z14)-;
- —O—;
- —S—;
- —SO2-;
- —CO—;
- or —Si(Z13)(Z14)-;
- Z13 and Z14 are the same as or different from each other, and each independently hydrogen;
- deuterium;
- a halogen group;
- a substituted or unsubstituted alkyl group;
- or a substituted or unsubstituted aryl group;
- T13 and T14 are the same as or different from each other, and each independently hydrogen;
- deuterium;
- a halogen group;
- a nitrile group;
- a nitro group;
- a hydroxyl group;
- a substituted or unsubstituted alkyl group;
- a substituted or unsubstituted cycloalkyl group;
- a substituted or unsubstituted alkoxy group;
- a substituted or unsubstituted alkenyl group;
- a substituted or unsubstituted silyl group;
- a substituted or unsubstituted amine group;
- a substituted or unsubstituted aryl group;
- or a substituted or unsubstituted heteroaryl group, t13 and t14 are an integer of 0 to 4, and when t13 and t14 are an integer of 2 or greater, substituents in the parentheses are the same as or different from each other,
- however, X12 is —C(Z13)(Z14)-;
- or —Si(Z13)(Z14)-, and Z13 and Z14 are the same as or different from each other and each independently an alkyl group substituted with a halogen group, or
- X12 is a direct bond;
- —C(Z13)(Z14)-;
- —O—;
- —S—;
- —SO2-;
- —CO—;
- or —Si(Z13)(Z14)-, and when Z13 and Z14 are not an alkyl group substituted with a halogen group, T13 and T14 are the same as or different from each other and each independently a halogen group;
- an alkyl group substituted with a halogen group;
- or an aryl group substituted with a halogen group, and t13 and t14 are an integer of 1 to 4.
76 more elements
Dependencies are inferred from the claim text.