Method for removing a pollutant from aqueous solution with a crosslinked polymer
AssigneeKing Fahd University of Petroleum and Minerals
InventorsNisar Ullah, Abdul Waheed, Muhammad Mansha, Izzat Wajih Kazi
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Abstract
A crosslinked resin made up of polymerized units of a linear polyamine with at least 3 primary and/or secondary amine functionalities and a bisacrylamide. The crosslinked polymers are porous spherical particles with a BET surface area in the range of 50-120 m2/g. A method of the synthesizing the crosslinked polymer is specified. A method for using the crosslinked resin as an adsorbent material in removing pollutants including organic dyes (e.g. Congo red, Rhodamine B) and heavy metals from an aqueous solution or an industrial wastewater sample is also described.
Claims19
A method for removing a pollutant from an aqueous solution, the method comprising:
- contacting the aqueous solution having an initial concentration of the pollutant with a crosslinked polymer to form a mixture;
- and
- filtering the mixture to obtain an aqueous solution having a reduced concentration of the pollutant compared to the initial concentration,
- wherein the crosslinked polymer comprises reacted units of
- a first monomer of formula (I)
- or a salt thereof, a solvate thereof, a tautomer thereof, a stereoisomer thereof, or a mixture thereof;
- and
- a second monomer of formula (II)
- or a salt thereof, a solvate thereof, a stereoisomer thereof, or a mixture thereof;
- wherein:
- R1, R3 and R4 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl, an optionally substituted cycloalkyl, an optionally substituted arylalkyl, and an optionally substituted aryl;
- R5, R6 and R7 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl, an optionally substituted cycloalkyl, an optionally substituted arylalkyl, a carboxy, a hydroxy, and a halogen;
- R8, R9, R10, R11, R12 and R13 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl, an optionally substituted cycloalkyl, an optionally substituted arylalkyl, and an optionally substituted aryl;
- and
- x, y, and z are independently an integer in a range of 1 to 6.
Dependencies are inferred from the claim text.