Polycarbonate resin composition
AssigneeMitsubishi Engineering-Plastics Corporation
InventorMinoru Soma
Life of this patent
Estimating the term…
Abstract
A polycarbonate resin composition comprising, 100 mass parts of (A1) a polycarbonate resin that contains a polycarbonate resin having a structural unit of the following general formula (1) and (A2) a polycarbonate resin having a structural unit of the general formula (2) in a mass ratio (A1)/(A2) of 100/0 to 10/90; 3 to 20 mass parts of a phosphorus flame retardant (B); 2 to 20 mass parts of a silicone flame retardant (C); and 3 to 100 mass parts of an inorganic filler (D), wherein the phosphorus flame retardant (B) is a phosphazene compound and/or a condensed phosphate ester, [C1]
Claims13
A polycarbonate resin composition, comprising:
- 100 mass parts of a polycarbonate resin comprising a polycarbonate resin (A1) having a structural unit of formula (1) and a polycarbonate resin (A2) having a structural unit of formula (2) in a mass ratio (A1)/(A2) of (less than 10)/(more than 90) to 0/100;
- 13 to 40 mass parts of a phosphorus flame retardant (B);
- 2 to 40 mass parts of a silicone flame retardant (C), which is a polyorganosiloxane-containing graft copolymer;
- and
- 30 to 100 mass parts of talc (D),
- wherein the phosphorus flame retardant (B) is a condensed phosphate ester compound of formula (3)
- where:
- R1, R2, R3, and R4 each represent an alkyl group having 1 to 6 carbons or an aryl group having 6 to 20 carbons which are optionally substituted by an alkyl group;
- p, q, r, and s are each 0 or 1;
- k is an integer from 1 to 5;
- and X1 represents an arylene group,
- the phosphorus flame retardant (B) does not contain a phosphazene compound or contains a phosphazene compound in a content of less than 3 mass parts,
- a total content of the phosphorus flame retardant (B) and the silicone flame retardant (C) is 24 to 40 mass parts per 100 mass parts of a total of the polycarbonate resins (A1) and (A2), and
- a ratio [(B)+(C)]/(D) between the total content of the phosphorus flame retardant (B) and the silicone flame retardant (C) and the content of the talc (D) is not more than 1.04,
- wherein in formula (1), R1 represents a methyl group;
- R2 represents a hydrogen atom or a methyl group;
- X represents
- wherein, R3 and R4 represent a hydrogen atom or a methyl group;
- and Z represents a group that binds to the carbon atom C to form an optionally substituted alicyclic hydrocarbon having 6 to 12 carbons,
- wherein in formula (2), X is as defined for formula (1).
Dependencies are inferred from the claim text.