R—Fe—B sintered magnet and production method therefor
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsTetsuya Ohashi, Koichi Hirota, Hajime Nakamura
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AssigneeShin-Etsu Chemical Co., Ltd.
InventorsTetsuya Ohashi, Koichi Hirota, Hajime Nakamura
Estimating the term…
R—Fe—B sintered magnet has a main phase containing R2(Fe,(Co))14B intermetallic compound and a grain boundary phase. The inter-particle grain boundary includes an expanded width part that is surrounded by a narrow width part at which the inter-particle width is 10 nm or less and that has a structure distended in the inter-particle width direction as compared with the grain boundary width of the narrow width part; the inter-particle width at the expanded width part is at least 30 nm; Fe/R ratio in the expanded width part is 0.01-2.5; the main phase includes, in the surface part thereof, an HR-rich phase represented by (R′,HR)2(Fe,(Co))14B (R′ represents rare-earth elements excluding Dy, Tb, and Ho, and that essentially include Nd; and HR represents Dy, Tb, and Ho); the contained amount of HR in the HR-rich phase is higher than that in the central part of the main phase.
An R—Fe—B base sintered magnet having a composition consisting essentially of 12 to 17 at % of R which is two or more elements selected from rare earth elements inclusive of yttrium and essentially contains Nd, 0.1 to 3 at % of M1 which is at least one element selected from among Si, Al, Mn, Ni, Cu, Zn, Ga, Ge, Pd, Ag, Cd, In, Sn, Sb, Pt, Au, Hg, Pb, and Bi, 0.05 to 0.5 at % of M2 which is at least one element selected from among Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, and W, 4.8+2×m to 5.9+2×m at % of B wherein m is at % of element M2, up to 10 at % of Co, up to 0.5 at % of C, up to 1.5 at % of O, up to 0.5 at % of N, and the balance of Fe, and comprising a main phase containing an intermetallic compound R2(Fe,(Co))14B and a grain boundary phase, wherein
Dependencies are inferred from the claim text.