Polyester
AssigneeBASF SE
InventorsMichael Bernhard Schick, Motonori Yamamoto
Life of this patent
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Abstract
The present invention relates to a polyester consisting of (A) repeat units derived from an acid component, which consists of (a1) 2,5-furandicarboxylic acid, (a2) an aliphatic C4-C36 dicarboxylic acid or a mixture of a plurality of aliphatic C4-C36 dicarboxylic acids, and (a3) a sulfonate group-containing dicarboxylic acid, and of (B) repeat units derived from a di-ol/amine component, and optionally of further repeat units (C) and/or branching components (E), and of (D) repeat units derived from at least one di- or oligofunctional compound selected from the group consisting of a di- or oligoisocyanate and a di- or oligoisocyanurate. In addition, the present invention relates to the production of these polyesters and their use.
Claims19
A polyester consisting of:
- A) repeat units derived from an acid component, which consists of
- a1) 30 to 90 mol %, based on the sum of components a1, a2, and a3, of 2,5-furandicarboxylic acid,
- a2) 0 to 60 mol %, based on the sum of components a1, a2, and a3, of an aliphatic C4-C36 dicarboxylic acid or a mixture of a plurality of aliphatic C4-C36 dicarboxylic acids, and
- a3) 10 to 60 mol %, based on the sum of components a1, a2, and a3, of a sulfonate group-containing dicarboxylic acid,
- wherein a3 is an aromatic sulfonate group-containing dicarboxylic acid in which the sulfonate group is present either as the free acid or as a salt, and a3 is selected from the group consisting of 1,4-benzenedicarboxylic acid-2-sulfonic acid, 1,3-benzenedicarboxylic acid-5-sulfonic acid, 1,2-benzenedicarboxylic acid-3-sulfonic acid, and 1,2-benzenedicarboxylic acid-4-sulfonic acid, in each case in the form of the free acid or of a salt, and
- wherein the molar percentages of components a1) to a3) together add up to 100 mol %,
- B) repeat units derived from a di-ol/amine component consisting of
- b1) a C2 to C12 alkanediol or a mixture of a plurality of C2 to C12 alkanediols, and/or
- b2) a dihydroxy compound of formula I,
- HO—[(CH2)n—O]m—H (I)
- where n is 2, 3 or 4 and m is an integer from 2 to 250,
- or a mixture of a plurality of such dihydroxy compounds,
- b3) optionally one or more amino C2 to C12 alkanols or one or more amino C5 to C10 cycloalkanols or mixtures thereof, and
- b4) optionally one or more diamino C1 to C8 alkanes,
- wherein the amount of B is chosen so that for every 100 mol of A there is 100 mol of B present, minus the number of moles of D and E,
- and wherein a sum of b1 and b2 in B is at least 50 mol %,
- C) optionally repeat units derived from
- c1) one or more hydroxycarboxylic acids of formula IIa,
- HO—C(O)-G-OH (IIa)
- where G represents a radical selected from the group consisting of phenylene, —(CH2)q—, in which q is an integer from 1 to 5, —C(R)H—, and —C(R)HCH2, in which R is methyl or ethyl, and/or
- c2) one or more aminocarboxylic acids or cyclic amides thereof selected from the group consisting of caprolactam, 1,6-aminocaproic acid, laurolactam, 1,12-aminolauric acid, and 1,11-aminoundecanoic acid,
- wherein the proportion of C in the total mass of the polyester is not more than 20% by weight,
- D) 0.1 to 4% by weight, based on the sum of components A, B, and C, of repeat units derived from at least one di- or oligofunctional compound selected from the group consisting of a di- or oligoisocyanate and a di- or oligoisocyanurate, and
- E) 0.1 to 4% by weight, based on the sum of components A, B, and C, of repeat units derived from a branching component that contains at least three functional groups, wherein the functional groups are selected from the group consisting of COOH, OH, NH2, and mixtures thereof.
Dependencies are inferred from the claim text.