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US 11,597,794 B2Granted
Coating compositions and coatings produced therefrom with improved soiling resistance and (self-)cleaning properties and use thereof
AssigneeBASF Coatings GmbH
InventorsChristian Weiher, Berthold Austrup, Andreas Janssen
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Abstract
Coating compositions and coatings with improved soiling resistance and (self-)cleaning properties are disclosed. The coating compositions and coatings may be nonaqueous coating compositions and may include at least one hydroxyl group-containing compound, at least one isocyanate group-containing compound having free or blocked isocyanate and silane groups, at least one catalyst for the crosslinking of the silane groups, and at least one alkoxysilyl-functional siloxane.
Claims19
A nonaqueous coating composition comprising:
- (A) at least one hydroxyl group-containing compound (A) having a hydroxyl number of 100 to 400 mg KOH/g and a Tg>−35° C., which is present at not less than 25 wt %, based on the binder fraction of the coating composition,
- (B) at least one isocyanate group-containing compound (B) having free or blocked isocyanate groups, compound (B) comprising at least one structural unit of the formula (I)
- —NR—(X—SiR″x(OR′)3-x) (I),
- and/or at least one structural unit of the formula (II),
- —N(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (II),
- where
- R=hydrogen, alkyl, cycloalkyl, aryl, or aralkyl, it being possible for the carbon chain to be interrupted by nonadjacent oxygen, sulfur, or NRa groups, with Ra=alkyl, cycloalkyl, aryl, or aralkyl,
- R′=hydrogen, alkyl, or cycloalkyl, it being possible for the carbon chain to be interrupted by nonadjacent oxygen, sulfur, or NRa groups,
- X, X′=linear and/or branched alkylene or cycloalkylene radical having 1 to 20 carbon atoms,
- R”=alkyl, cycloalkyl, aryl, or aralkyl, it being possible for the carbon chain to be interrupted by nonadjacent oxygen, sulfur, or NRa groups,
- n=0 to 2, m=0 to 2, m+n=2, and x, y=0 to 2,
- and
- (C) at least one catalyst (C) for the crosslinking of silane groups,
- wherein additionally there is
- (D) at least one alkoxysilyl-functional siloxane of the formula (III)
- R1—SiR22-Ax-By—O—SiR32—R4 (III)
- in which
- A is a group —[O—SiR52]— and B is a group —[O—SiR6R7]—,
- R2, R3, R5, and R6 independently of one another are linear or branched alkyl groups having 1 to 4 carbon atoms,
- R1, R4, and R7 independently of one another are a group -L-R8,
- in which L=a linear or branched divalent alkyl group and
- R8=H or —Si(R9)z(OR10)3-z with R9, R10=a linear or branched alkyl group having 1-4 carbon atoms and z=0, 1, or 2,
- with the proviso that at least one of the radicals R1 or R4 and/or at least one group B constitutes a group R8=—Si(R9)z(OR10)3-z,
- x independently is an integer of 1-20,
- y independently is an integer of 0-10.
22 more elements
Dependencies are inferred from the claim text.