Alkaline earth metal titanate crystal laminate
AssigneeJapan Science and Technology Agency
InventorTakashi Tachikawa
Life of this patent
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Abstract
There are provided a new type of crystal laminate of an alkaline earth metal titanate having improved catalytic activity, and a method for producing the same. The crystal laminate is provided having a crystal of the alkaline earth metal titanate as a constitutional unit, wherein the crystal being the constitutional unit is a cubic crystal, a tetragonal crystal or an orthorhombic crystal; the crystal being the constitutional unit has a primary particle diameter of 500 nm or less; and the crystal is layered with an orientation in a {100} plane direction thereof.
Claims3
A structure having an alkaline earth metal titanate crystal nanoparticle on a surface of a crystal laminate,
- wherein the crystal laminate comprises:
- a crystal of an alkaline earth metal titanate as a constitutional unit, wherein:
- the crystal is a cubic crystal, a tetragonal crystal or an orthorhombic crystal;
- the crystal has a primary particle diameter of 500 nm or less;
- and
- the crystal is layered with an orientation in a {100} plane direction thereof,
- wherein
- the crystal laminate has an average width of more than 1 μm,
- the crystal laminate has an average thickness of 50 am or more,
- the crystal laminate has a ratio (average width/average thickness of the average width to the average thickness of 10 to 100,
- the crystal present on a surface of the crystal laminate has a primary particle diameter of 2 to 20 times more than a primary particle diameter of the crystal present in an interior of the crystal laminate,
- the crystal laminate has a specific surface area of 10 m2/g or more,
- a crystal orientation of the alkaline earth metal titanate crystal nanoparticle is in the same direction as that of the crystal laminate,
- the alkaline earth metal titanate crystal nanoparticle has a primary particle diameter of twice or more a primary particle diameter of the crystal present on the surface of the crystal laminate,
- a proportion of the nanoparticles on the surface of the crystal laminate is, in terms of surface coverage, 20% to 80%, and
- the alkaline earth metal titanate crystal nanoparticle has a primary particle diameter of 50 nm or more.
Dependencies are inferred from the claim text.