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US 11,583,830 B2Granted
Process for recovery of lithium from brine
AssigneeStandard Lithium Ltd.
InventorCraig Johnstone Brown
Life of this patent
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Abstract
A process for recovery of lithium ions from a lithium-bearing brine includes contacting the lithium-bearing brine with a lithium ion sieve (where that LIS includes an oxide of titanium or niobium) in a first stirred reactor to form a lithium ion complex with the lithium ion sieve, and decomplexing the lithium ion from the lithium ion sieve in a second stirred reactor to form the lithium ion sieve and an acidic lithium salt eluate.
Claims24
A process for recovery of lithium ions from a lithium-bearing brine, the process comprising:
- contacting the lithium-bearing brine with a lithium ion sieve for less than about one hour in a first reactor to form a lithium ion complex with the lithium ion sieve;
- separating the lithium ion complex with the lithium ion sieve from the brine with a solid/liquid separation device;
- contacting the lithium ion complex with the lithium ion sieve with water before decomplexing in a second reactor;
- and
- decomplexing lithium ions from the lithium ion sieve in the second reactor to form an acidic lithium salt eluate solution separated from the lithium ion sieve;
- separating the lithium ion sieve from the acidic lithium salt eluate solution with a solid/liquid separation device;
- and
- contacting the lithium ion sieve with water after decomplexing in the second reactor to obtain a regenerated lithium ion sieve and a dilute acid water wash;
- wherein the lithium ion sieve comprises an oxide of titanium or niobium;
- wherein a pH of the first reactor is maintained at a constant value through addition of an alkali;
- wherein the decomplexing is performed by elution using an acid;
- wherein an average contact time of the lithium ion complex with the lithium ion sieve and the acid is less than 1 hour;
- wherein a concentration of the acid is maintained at a constant value through additions of said acid;
- and
- wherein the concentration of the acid is less than 0.1 M.
12 more elements
Dependencies are inferred from the claim text.