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US 11,572,422 B2Granted
Recyclable cross-linked diene elastomers comprising furanyl groups and precursors thereof
AssigneesUniversite De Bordeaux, Institut Polytechnique De Bordeaux, Centre National De La Recherche Scientifique
InventorsFrédéric Peruch, Pierre Berto, Stéphane Grelier
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Abstract
The present invention concerns new precursors of recyclable cross-linked diene elastomers comprising at least one furanyl group along the chain and comprising chain-end units with furanyl groups, their use in the preparation of said recyclable elastomers and their process of preparation. The invention also concerns new recyclable cross-linked diene elastomers, their preparation process and their uses.
Claims13
A compound having the following formula (I):
- wherein:
- m is an integer comprised between 1 and 10,000;
- B1 and B2, independently of each other, have the following formula (B):
- or the following formula (C):
- wherein:
- X is:
- a bond or
- a group of formula —NH—X1—, wherein X1 is a linear or branched (C1-C5)alkylene group;
- Y is selected from the linear and branched (C1-C5)alkylene groups;
- Z and Z′ are independently of each other —O— or —NH—;
- W and W′ are independently of each other selected from the group consisting of:
- -C(═O)—NH—Y′—, —C(═O)—Y′—, and —Y′— groups, Y′ representing a linear or branched (C1-C5)alkylene group;
- Ra is selected from the group consisting of:
- H, linear or branched (C1-C5)alkyl, and halogen atom;
- A comprises at least one repeating unit having the following formula (U1)
- and at least one repeating unit having one of the following formulae (U′1) and (U′2):
- and optionally at least one further repeating unit having the following formula (U2):
- wherein the repeating units of A are randomly distributed, and
- wherein A comprises at least 5% in number of units (U1) in relation to the total number of units (U1), (U2), (U′ 1), and (U′2);
- wherein:
- Ra is as defined above;
- Ra″ is selected from the group consisting of H, —CH═CH2, and —C(═CH2)(Ra), Ra being as defined above;
- Rb is H and Rc is B3 having the formula (C) as defined above, or Rb is B3 having the formula (C) as defined above and Rc is H;
- A′ is chosen from the following groups:
- Ra and B3 being as defined above.
22 more elements
Dependencies are inferred from the claim text.