Lithographic printing plate precursor, method for making lithographic printing plate, organic polymer particle, and photosensitive resin composition
AssigneeFUJIFILM Corporation
InventorsAtsuyasu Nozaki, Kenjiro Araki
Life of this patent
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Abstract
A lithographic printing plate precursor having an image-recording layer on a hydrophilic support, in which the image-recording layer includes an organic polymer particle, and the organic polymer particle is a reaction product obtained by at least reacting an aromatic polyvalent isocyanate compound having a structure represented by Formula PO and water, a method for making a lithographic printing plate having excellent printing resistance in the case of using an ultraviolet-curable ink in printing, a new organic polymer particle, and a resin composition including the organic polymer particle.
Claims16
A lithographic printing plate precursor comprising:
- an image-recording layer on a hydrophilic support,
- wherein the image-recording layer includes an organic polymer particle, and
- the organic polymer particle has a structure derived from an aromatic polyvalent isocyanate compound having a structure represented by Formula PO, and has a net structure formed by a urea bond,
- in Formula PO, RPO1 represents an alkylene group, n represents an integer of 2 to 200, RPO2 represents an alkyl not including a radical polymerizable group, and * represents a bonding site to other structures, and
- wherein the aromatic polyvalent isocyanate compound having the structure represented by Formula PO includes a compound having a structure represented by Formula A-1 and a structure represented by Formula B-1,
- in Formula A-1, ArA represents an aromatic ring structure, LA's each independently represent a single bond or a divalent linking group, nA1 represents an integer of 1 to 4, RA's each independently represent a monovalent group, nA2 represents an integer of 0 to 3, * and a wavy line portion each independently represent a bonding site to other structures, and mA represents 0 or 1, and
- in Formula B-1, ArB represents an aromatic ring structure, LB's each independently represent a single bond or a divalent linking group, RPO's each independently represent a group including the structure represented by Formula PO, nB1 represents an integer of 1 to 4, RB' s each independently represent a monovalent substituent, nB2 represents an integer of 0 to 3, * and a wavy line portion each independently represent a bonding site to other structures, and mB represents 0 or 1.
A photosensitive resin composition comprising:
- an organic polymer particle;
- an infrared absorber;
- a polymerizable compound;
- and
- a polymerization initiator,
- wherein the organic polymer particle has a structure derived from an aromatic polyvalent isocyanate compound having a structure represented by Formula PO, and has a net structure formed by a urea bond,
- in Formula PO, RPO1 represents an alkylene group, n represents an integer of 2 to 200, RPO2 represents an alkyl not including a radical polymerizable group, and * represents a bonding site to other structures, and
- wherein the aromatic polyvalent isocyanate compound having the structure represented by Formula PO includes a compound having a structure represented by Formula A-1 and a structure represented by Formula B-1,
- in Formula A-1, ArA represents an aromatic ring structure, LA's each independently represent a single bond or a divalent linking group, nA1 represents an integer of 1 to 4, RA's each independently represent a monovalent group, nA2 represents an integer of 0 to 3, * and a wavy line portion each independently represent a bonding site to other structures, and mA represents 0 or 1, and
- in Formula B-1, ArB represents an aromatic ring structure, LB's each independently represent a single bond or a divalent linking group, RPO's each independently represent a group including the structure represented by Formula PO, nB 1 represents an integer of 1 to 4, RB's each independently represent a monovalent substituent, nB2 represents an integer of 0 to 3, * and a wavy line portion each independently represent a bonding site to other structures, and mB represents 0 or 1.
Dependencies are inferred from the claim text.