Method of making a hydrodesulfurization catalyst with a structural directing surfactant
AssigneeKing Fahd University of Petroleum and Minerals
InventorsKhalid R. Alhooshani, Saheed Adewale Ganiyu, Abdulkadir Tanimu
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Abstract
A method of preparing hydrodesulfurization catalysts having cobalt and molybdenum sulfide deposited on a support material containing mesoporous silica. The method utilizes a sulfur-containing silane that dually functions as a silica source and a sulfur precursor. The method involves an one-pot strategy for hydrothermal treatment and a single-step calcination and sulfidation procedure. The application of the hydrodesulfurization catalysts in treating a hydrocarbon feedstock containing sulfur compounds to produce a desulfurized hydrocarbon stream is also specified.
Claims14
A method of preparing a CoMoS hydrodesulfurization catalyst, the method comprising:
- mixing a structural directing surfactant with an acidic aqueous solution to form a first solution,
- adding a mercaptoalkyltrialkoxysilane to the first solution to form a second solution,
- mixing the second solution with a molybdenum precursor and a cobalt precursor to form a reaction mixture;
- hydrothermally treating the reaction mixture to form a dried mass;
- and
- calcining the dried mass in an activation gas thereby forming the CoMoS hydrodesulfurization catalyst,
- wherein:
- the activation gas is at least one selected from the group consisting of air, argon, nitrogen, helium, hydrogen, and carbon monoxide;
- and
- the CoMoS hydrodesulfurization catalyst is disposed on a support material comprising a mesoporous silica.
Dependencies are inferred from the claim text.