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US 11,560,480 B2Granted
High wet fast disperse dye mixtures of N-[4-(5-fluoro-2,4-dinitro-phenylazo)-phenyl]-amine derivatives and N-[4-(4-nitro-phenylazo)-phenyl]-amine derivatives
AssigneeDyStar Colours Distribution GmbH
InventorsAdrian Murgatroyd, Manfred Hoppe, Clemens Grund, Fanny Vermandel, Chongjun Jiao
Life of this patent
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Abstract
The present invention is directed to dye mixtures comprising dyes of formula (1) and dyes of formula (2), the process of the production and the use of the dye mixtures.
Claims14
A dye mixture comprising
- at least one dye of formula (1)
- wherein independent of each other
- R1 is hydrogen, (C1-C4)-alkyl or C1-C4-alkoxy,
- R2 is hydrogen, carboxy, (C1-C4)-alkyl, halogen, acylamino, —NHCO-aryl, —NHCO-benzyl) or sulfonylamino,
- R3 and R4 is hydrogen, (C1-C4)-alkyl, (CH2)n-phenyl, CH2—CH═CH2, (CH2)n—OH, (CH2)n—O—(C1-C4)-alkyl, (CH2)n—O-phenyl, (CH2)n—O-benzyl, (CH2)—O—(CH2)m—OH, (CH2)n—O—(CH2)m—O—(C1-C4)-alkyl, (CH2)—O—(CH2)m—O-phenyl, (CH2)—O—(CH2)m—O-benzyl, (CH2)n—COOH, (CH2)n—COO—(C1-C4)-alkyl, (CH2)n—COO-phenyl, (CH2)n—COO-benzyl, (CH2)n—CN, (CH2)n—COO(CH2)m—CO—(C1-C4)-alkyl, (CH2)n—COO(CH2)m—CO-phenyl, (CH2)n—COO(CH2)m—CO-benzyl, (CH2)n—O—CO—(C1-C4)-alkyl, (CH2)n—O—CO-phenyl, (CH2)n—O—CO-benzyl, COO—(CH2)n-2-furfuryl, (CH2)m—O—(CH2)n-2-furfuryl, CHR9—(CH2)p—(C1-C4)-alkyl, CHR9—(CH2)p phenyl, CHR9—CH═CH2, CHR9—(CH2)p—OH, CHR9—(CH2)p—O—(C1-C4)-alkyl, CHR9—(CH2)p—O-phenyl, CHR9—(CH2)p—O-benzyl, CHR9—(CH2)p—O—(CH2)m—OH, CHR9—(CH2)p—O—(CH2)m—O—(C1-C4)-alkyl, CHR9—(CH2)p—O—(CH2)m—O-phenyl, CHR9—(CH2)p—O—(CH2)m—O-benzyl, CHR9—(CH2)p—COOH, CHR9—(CH2)p—COO—(C1-C4)-alkyl, CHR9—(CH2)p—COO-phenyl, CHR9—(CH2)p—COO-benzyl, CHR9—(CH2)p—CN, CHR9—(CH2)p—COO(CH2)m—CO—(C1-C4)-alkyl, CHR9—(CH2)p—COO(CH2)m—CO-phenyl, CHR9—(CH2)p—COO(CH2)m—CO-benzyl, CHR9—(CH2)p—O—CO—(C1-C4)-alkyl, CHR9—(CH2)p—O—CO-phenyl, CHR9—(CH2)p—O—CO-benzyl, CHR9—(CH2)p-2-furfuryl or CHR9—(CH2)p—O—(CH2)n-2-furfuryl,
- wherein
- R9 is (C1-C4)-alkyl or (C1-C4)-alkyl substituted by —OH or halogen,
- n is 1 to 4,
- m is 1 to 4 and
- p is 0 to 3,
- with the proviso that at least one of R3 and R4 is not hydrogen,
- and
- at least one dye of formula (2)
- wherein independent of each other
- R5 and R6 is hydrogen, (C1-C4)-alkyl, (CH2)n-phenyl, CH2—CH═CH2, (CH2)n—OH, (CH2)n—O—(C1-C4)-alkyl, (CH2)n—O-phenyl, (CH2)n—O-benzyl, (CH2)n—O—(CH2)m—OH, (CH2)n—O—(CH2)m—O—(C1-C4)-alkyl, (CH2)n—O—(CH2)m—O-phenyl, (CH2)n—O—(CH2)m—O-benzyl, (CH2)n—COOH, (CH2)n—COO—(C1-C4)-alkyl, (CH2)n—COO-phenyl, (CH2)n—COO-benzyl, (CH2)n—CN, (CH2)n—COO(CH2)m—CO—(C1-C4)-alkyl, (CH2)n—COO(CH2)m—CO-phenyl, (CH2)n—COO(CH2)m—CO-benzyl, (CH2)n—O—CO—(C1-C4)-alkyl, (CH2)n—O—CO-phenyl, (CH2)n—O—CO-benzyl, COO—(CH2)n-2-furfuryl or (CH2)m—O—(CH2)n-2-furfuryl,
- wherein
- n is 1 to 4 and
- m is 1 to 4,
- with the proviso that at least one of R5 and R6 is not hydrogen,
- R10 is hydrogen, (C1-C4)-alkyl or (C1-C4)-alkoxy,
- R11 is hydrogen, carboxy, (C1-C4)-alkyl, halogen, acylamino, —NHCO-aryl, —NHCO-benzyl) or sulfonylamino,
- X5 and X6 is hydrogen, halogen, nitro or cyano,
- with the proviso that at least one of X5 and X6 is not hydrogen.
20 more elements
Dependencies are inferred from the claim text.