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US 11,560,347 B2Granted
Method for producing fluorovinyl ether compound
AssigneeDaikin Industries, Ltd.
InventorsNaoyuki Hoshiya, Akihiro Gotou, Yosuke Kishikawa
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Abstract
A method for synthesizing a fluorovinyl ether compound from a fluorine-containing vinyl compound. Specifically, a method for producing a compound represented by formula (1), comprising step A of reacting a compound represented by formula (2) with a compound represented by formula (3) in the presence of a transition metal catalyst: wherein the substituents are defined in the disclosure.
Claims14
A method for producing a compound represented by formula (1):
- wherein
- Ra1 is a hydrogen atom, a halogeno group, an alkyl group, a fluoroalkyl group, or an aromatic group optionally having one or more substituents,
- Rf is a fluoro group or a perfluoroalkyl group,
- Ra2 is a hydrogen atom, a halogeno group, an alkyl group, a fluoroalkyl group, or an aromatic group optionally having one or more substituents, or
- Ra1 and Ra2 may be linked to each other,
- Rb1 is RS,
- Rb2 is a hydrogen atom or RS,
- Rb3 is a hydrogen atom or RS, or
- two or three of Rb1, Rb2, and Rb3, taken together with the adjacent carbon atom, may form a ring optionally having one or more substituents, and
- RS, in each occurrence, is the same or different and represents a hydrocarbon group optionally having one or more substituents,
- the method comprising
- step A of reacting a compound represented by formula (2):
- wherein
- Rx is a leaving group and is selected from the group consisting of a halogeno group, a sulfonic acid ester group, a fluorosulfonyl group, a nitro group, or a cyano group, and
- other symbols are as defined above,
- with a compound represented by formula (3):
- wherein the symbols in the formula are as defined above,
- in the presence of a transition metal catalyst.
15 more elements
Dependencies are inferred from the claim text.