Aqueous coating composition for corrosion protection
AssigneeAllnex Austria GmbH
InventorsFlorian Lunzer, Armin Temel, Gerald Hobisch, Oliver Etz
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Abstract
The invention relates to an aqueous resin dispersion D comprising a mixture of a hydrophilically modified epoxy-based resin P and a resole R, and a co-crosslinker E, to a process for the preparation of the aqueous resin dispersion D, and to a method of use thereof to prepare coating films to prevent corrosion of the coated substrate.
Claims10
An aqueous resin dispersion D comprising a mixture of a hydrophilically modified epoxy-based resin P and a resole R, and a co-crosslinker E, wherein the hydrophilically modified epoxy-based resin P is made in a reaction or a sequence of reactions which includes at least one step where an advancement reaction is conducted,
- wherein the hydrophilically modified epoxy-based resin P is a non-ionically modified epoxy-based resin Pn,
- wherein the non-ionically modified epoxy-based resin Pn is made by
- synthesizing an emulsifier F which has a nonionic portion which comprises a polyoxyethylene homopolymer or copolymer segment or a sugar alcohol segment, and a non-hydrophilic and compatibilising portion which comprises building blocks derived from epoxide compounds which are at least difunctional, by coupling of the at least difunctional epoxide compounds with hydroxy-functional polyoxyethylene homopolymers or hydroxy-functional polyoxyethylene copolymers or with sugar alcohols catalysed with strong Brønsted acids or Lewis acids, or with epoxide-functional polyoxyethylene homopolymers or epoxide-functional polyoxyethylene copolymers or with epoxide-functional sugar alcohols, and
- incorporation of the emulsifier F into an epoxy resin via an advancement reaction with a diepoxide A1, a dihydric aromatic compound A2, and the emulsifier F, in the presence of a phosphine or amine catalyst, wherein the stoichiometry is chosen such that the advancement reaction product has epoxide end groups, and
- wherein the co-crosslinker E is selected from the group consisting of
- a compound E1 having at least two hydroxyl groups that react with acid compounds present in a coating composition at elevated temperature above 80° C. under ester formation and liberation of water, and
- an ester E2 with at least two ester groups formed by an at least dihydric alcohol E22 and an acid E21 which acid is unstable at elevated temperature above 80° C.
Dependencies are inferred from the claim text.