Sulfonium salt photoinitiator, preparation method therefor, photocurable composition comprising sulfonium salt photoinitiator, and use thereof
AssigneesChangzhou Tronly New Electronic Materials Co., Ltd., Changzhou Tronly Advanced Electronic Materials Co., Ltd.
InventorXiaochun Qian
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Abstract
The present invention provides a sulfonium salt photoinitiator, a preparation method therefor, a photocurable composition comprising sulfonium salt photoinitiator, and use thereof. The sulfonium salt photoinitiator has a structure represented by formula (I). By modifying the structure of an existing sulfonium salt photoinitiator, a sulfonium salt photoinitiator having a new structure is obtained, which can exhibits a higher photosensitivity and an excellent as well as characteristics of low odor and low toxicity, when being used in a photocurable composition. This is significantly superior to existing similar photoinitiators.
Claims20
A sulfonium salt photoinitiator, wherein the sulfonium salt photoinitiator has a structure represented by formula (I):
- wherein Ar1 is an aryl group or a substituted aryl group;
- Ar2 is
- wherein R6 and R6′ are each independently a C1 to C20 linear or branched alkyl group, a C3 to C20 cycloalkyl group, a C1 to C10 alkyl group substituted with a C3 to C8 cycloalkyl group, a C3 to C8 cycloalkyl group substituted with a C4 to C20 alkyl group, a C6 to C20 aryl group, a C3 to C20 heterocyclic group, or a C1 to C10 alkyl group substituted with a C6 to C14 aryl group, and n3 and n4 are each independently an integer of 0 to 4;
- R1′ is a C1 to C20 linear or branched alkyl group, a C3 to C20 cycloalkyl group, a C1 to C10 alkyl group substituted with a C3 to C8 cycloalkyl group, a C3 to C8 cycloalkyl group substituted with a C4 to C20 alkyl group, a C6 to C20 aryl group, a C2 to C20 heterocyclic group, or a C1 to C10 alkyl group substituted with a C6 to C14 aryl group;
- and Q is a single bond, O, S,
- and R3, R4, and R5 are each independently an organic substituent;
- R1 represents a C1 to C20 linear or branched alkyl group, a C3 to C20 cycloalkyl group, a C1 to C10 alkyl group substituted with a C3 to C8 cycloalkyl group, a C3 to C8 cycloalkyl group substituted with a C4 to C20 alkyl group, a C6 to C20 aryl group, a C2 to C20 heterocyclic group, or a C1 to C10 alkyl group substituted with a C6 to C14 aryl group;
- R2 and R2′ are each independently a C1 to C20 linear or branched alkyl group, a C3 to C20 cycloalkyl group, or a C1 to C10 alkyl group substituted with a C3 to C8 cycloalkyl group, and n1 and n2 each independently represent an integer of 0 to 4;
- M is a single bond, O, S,
- and R3, R4, and R5 are each independently an organic substituent;
- Y− represents an inorganic anion or an organic anion.
A compound selected from the group consisting of:
Dependencies are inferred from the claim text.