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US 11,530,486 B2Granted
Cleaning method and recording medium for recording cleaning program
AssigneeTokyo Electron Limited
InventorsDaisuke Shirasawa, Naoki Sato
Life of this patent
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Abstract
A cleaning method for a by-product including a refractory material or a metal compound includes a reforming process and an etching process. In the reforming process, a surface of the by-product is reformed using nitrogen-containing gas and hydrogen-containing gas. In the etching process, the reformed surface is etched using halogen-containing gas and inert gas.
Claims15
A method for cleaning a chamber inner wall of an etching apparatus, the method comprising:
- first reforming, by plasma generated from nitrogen-containing gas and hydrogen-containing gas, a surface oxide film of a refractory material or a metal compound attached to the chamber inner wall of the etching apparatus to form a reformed layer, and form a first damage layer below the reformed layer;
- first etching, by plasma generated from halogen-containing gas and inert gas, the formed reformed layer and the first damage layer to expose the refractory material or the metal compound;
- second reforming, by the plasma generated from the nitrogen-containing gas and the hydrogen-containing gas, the refractory material or the metal compound attached to the chamber inner wall of the etching apparatus to form a second damage layer;
- and
- second etching, by the plasma generated from the halogen-containing gas and the inert gas, the formed second damage layer,
- wherein the nitrogen-containing gas is N2.
3 more elements
A method for cleaning a chamber inner wall of an etching apparatus, the method comprising:
- first reforming, by plasma generated from nitrogen-containing gas and hydrogen-containing gas, a surface oxide film of a refractory material or a metal compound attached to the chamber inner wall of the etching apparatus to form a reformed layer, and form a first damage layer below the reformed layer;
- first etching, by plasma generated from fluorine-containing gas and inert gas, the formed reformed layer and the first damage layer to expose the refractory material or the metal compound;
- second reforming, by the plasma generated from the nitrogen-containing gas and the hydrogen-containing gas, the refractory material or the metal compound attached to the chamber inner wall of the etching apparatus to form a second damage layer;
- and
- second etching, by the plasma generated from the fluorine-containing gas and the inert gas, the formed second damage layer, wherein
- the first reforming and the second reforming include reducing a surface of the metal compound using the nitrogen-containing gas and the hydrogen-containing gas,
- the first etching and the second etching include etching the reduced surface using the fluorine-containing gas and the inert gas, and
- the second reforming and the second etching are repeated for a number of times after the first etching,
- wherein the nitrogen-containing gas is N2.
6 more elements
Dependencies are inferred from the claim text.