Pyrolysis tar conversion
AssigneeExxonMobil Chemical Patents Inc.
InventorsKapil Kandel, Glenn A. Heeter, Teng Xu, Giovanni S. Contello, Krystle J. Emanuele
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Abstract
This invention relates to a process for determining the suitability of pyrolysis tar, such as steam cracker tar, for upgrading using hydroprocessing without excessive fouling of the hydroprocessing reactor. A pyrolysis tar is sampled, the sample is analyzed to determine one or more characteristics of the tar related to tar reactivity, and the analysis is used to determine conditions under which the tar can be blended, pre-treated, and/or hydroprocessed.
Claims12
A process for producing a hydroprocessed steam cracker tar (“SCT”), the process comprising:
- (a) providing an SCT having a temperature T1≤350° C. and a reactivity RT≥28 Bromine Number units (“BN”), the SCT having a density at 15° C. ≥1.10 g/cm3 and viscosity at 50° C. ≥1000 cSt, wherein at least 70 wt. % of the SCT has a normal boiling point of at least 290° C.;
- (b) establishing a predetermined reference reactivity RRef≤18 BN;
- (c) carrying out either
- (i) conducting away at least a portion of the SCT or hydroprocessing at least a portion of the SCT under Mild Hydroprocessing Conditions, or
- (ii) producing a treated SCT by carrying out one or more of
- (A) one or more thermal treatments of at least a portion of the SCT by heating from T1 to a temperature THS, and maintaining the SCT at a temperature of at least THS for a time tHS of at least 10 minutes to produce a treated SCT, wherein THS is at least 10° C. greater than T1 and THS is in the range of 300° C. to 360° C. and tHS of ≥5 minutes, and
- (B) combining at least a portion of the SCT with a second SCT;
- and
- following steps (A) and/or (B) determining an RT of the treated SCT, and comparing RRef and the RT of the treated SCT, and
- (I) when RT of the treated SCT exceeds 12 BN, carrying out step (c)(i) or repeating steps (c)(ii)(A) and/or step (c)(ii)(B), or
- (II) when RT of the treated SCT does not exceed RRef, then conducting the treated SCT to step (d);
- and
- (d) hydroprocessing the treated SCT, the hydroprocessing being carried out under Standard Hydroproces sing Conditions in the presence of (i) a utility fluid, (ii) at least one catalyst, and (iii) a treatment gas comprising molecular hydrogen to produce a hydroprocessor effluent comprising hydroprocessed SCT, wherein the Standard Hydroprocessing Conditions include a temperature ≥200° C., a pressure ≥8 MPa, a weight hourly space velocity (“WHSV”, tar basis) ≥0.3 hr−1, and a molecular hydrogen consumption rate (tar basis) in the range of from 270 S m3/m3 to about 534 S m3/m3.
Dependencies are inferred from the claim text.