Back to results
US 11,530,320 B2Granted
Long carbon fibre reinforced polypropylene composition
AssigneeBorealis AG
InventorsThomas Lummerstorfer, Wolfgang Stockreiter, Michael Jerabek, Stefan Hochradl, Michael Tranninger
Life of this patent
Estimating the term…
Abstract
Polypropylene composition comprising a polypropylene base material, a carbon fibre and an adhesion promoter with an excellent impact/stiffness balance, its preparation, articles comprising the composition and the use of the composition.
Claims13
A polypropylene composition comprising:
- a. 37.0 to 95.0 wt %, based on a total weight of the polypropylene composition, of a polypropylene base material (PBM), wherein the polypropylene base material (PBM) comprises a propylene homopolymer (hPP) and a heterophasic propylene copolymer (HECO) in a weight ratio of propylene homopolymer (hPP) to heterophasic propylene copolymer (HECO) in a range of 1:5 to 1:25;
- and
- b. 4.5 to 50.0 wt %, based on the total weight of the polypropylene composition, of a carbon fiber (CF);
- and
- c. 0.5 to 13.0 wt %, based on the total weight of the polypropylene composition, of an adhesion promoter (AP),
- wherein the carbon fiber (CF) comprised in the polypropylene composition is a roving and has an average fiber length in a range of 4.0 to 17.0 mm, the polypropylene composition is present as particles with the components a) and c) forming a polymer matrix (PM) having a melt flow rate MFR2 (230° C., 2.16 kg) measured according to ISO 1133 in a range of 2.0 to 250 g/10 min and wherein an average particle length of the polypropylene composition corresponds to an average fiber length of the carbon fiber (CF), and wherein
- the propylene homopolymer (hPP) has
- a1. a melting temperature measured according to ISO 11357-3 of at least 150° C. and/or
- b1. a xylene cold soluble (XCS) content of 4.0 wt %, based on a total weight of the propylene homopolymer (hPP),
- the heterophasic propylene copolymer (HECO) has
- a2. a xylene cold soluble (XCS) content of >5.0 wt %, based on a total weight of the heterophasic propylene copolymer (HECO), and/or
- b2. a comonomer content of ≤30.0 mol %, based on a total weight of the heterophasic propylene copolymer (HECO), and
- wherein the polypropylene base material (PBM) and the adhesion promoter (AP) are the only polymeric compounds in the polypropylene composition.
10 more elements
A process for the preparation of a polypropylene composition comprising:
- a. 37.0 to 95.0 wt %, based on a total weight of the polypropylene composition, of a polypropylene base material (PBM) wherein the polypropylene base material (PBM) is:
- i. a propylene homopolymer (hPP) and/or
- ii. a propylene copolymer (cPP);
- and
- b. 4.5 to 50.0 wt %, based on the total weight of the polypropylene composition, of a carbon fiber (CF);
- and
- c. 0.5 to 13.0 wt %, based on the total weight of the polypropylene composition, of an adhesion promoter (AP),
- wherein the carbon fiber (CF) comprised in the polypropylene composition is a roving and has an average fiber length in a range of 4.0 to 17.0 mm, the polypropylene composition is present as particles with the components a) and c) forming a polymer matrix (PM) having a melt flow rate MFR2 (230° C., 2.16 kg) measured according to ISO 1133 in a range of 2.0 to 250 g/10 min and wherein an average particle length of the polypropylene composition corresponds to an average fiber length of the carbon fiber (CF), and wherein
- the propylene homopolymer (hPP) has
- a1. a melting temperature measured according to ISO 11357-3 of at least 150° C. and/or
- b1. a xylene cold soluble (XCS) content of ≤4.0 wt %, based on a total weight of the propylene homopolymer (hPP),
- the propylene copolymer (cPP) is a heterophasic propylene copolymer (HECO) having
- a2. a xylene cold soluble (XCS) content of >5.0 wt %, based on a total weight of the heterophasic propylene copolymer (HECO), and/or
- b2. a comonomer content of ≤30.0 mol %, based on a total weight of the heterophasic propylene copolymer (HECO), and
- wherein the polypropylene base material (PBM) and the adhesion promoter (AP) are the only polymeric compounds in the polypropylene composition,
- the process comprising steps of:
- a′. providing a polypropylene base material (PBM),
- b′. providing an adhesion promoter (AP),
- c′. melting the polypropylene base material (PBM) of step a) and melting the adhesion promoter (AP) of step b),
- d′. providing a carbon fiber (CF) as a continuous roving,
- e′. impregnating the carbon fiber (CF) of step d′) with a first part of the polypropylene base material (PBM1) and with a whole of the adhesion promoter (AP) of step c′) and subsequently coating a thus impregnated carbon fiber (CF) with a remaining second part of the polypropylene base material (PBM2) to obtain a carbon fiber (CF) reinforced polypropylene material, and
- f′. solidifying and cutting the carbon fiber (CF) reinforced polypropylene material into particles with an average particle length in a range of 4.0 to 17.0 mm to obtain the polypropylene composition.
19 more elements
Dependencies are inferred from the claim text.