A method for preparation of inorganic markers for security identification/marking on explosives, fuses, and ammunition after detonation and on firearms and metal projectiles, comprising:
- a solid-state reaction, wherein the inorganic oxides are packed in polyacetal reactors containing 0.1 mm diameter zirconia balls for grinding, using a planetary mill, at a speed of 360 rpm for 4 hours, followed by calcination, in resistive furnaces, at a temperature of 1100° C., for 4 hours, to obtain LaNbO4 (Mark1), BiVO4, Sr3V2O8 and YNbO4 (Mark2), according to the reactions:
- 0.89La2O3+Nb2O5+0.01Er2O3+0.10Yb2O3→2La0.89Er0.01Yb0.10NbO4
- 0.845Y2O3+Nb2O5+0.005Tm2O3+0.15Yb2O3→2Y0.845Tm0.005Yb0.15NbO4
- 0.89Bi2O3+V2O5+0.01Ho2O3+0.10Yb2O3→2Bi0.89Ho0.01Yb0.10VO4
- 2.88SrCO3+V2O5+0.03Ho2O3+0.09Yb2O3→Sr2.88Ho0.03Yb0.09V2O8+2.88CO2
- which are doped, respectively, with the rare-earth ion pairs:
- erbium (Er) and ytterbium (Yb), holmium (Ho) and ytterbium (Yb), holmium (Ho) and ytterbium (Yb) and, finally, thulium (Tm) and ytterbium (Yb).