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US 11,499,093 B2Granted
Rare earth complex and light emitting element
AssigneeNational University Corporation Hokkaido University
InventorsYuichi Kitagawa, Fumiya Suzue, Takayuki Nakanishi, Koji Fushimi, Yasuchika Hasegawa
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Abstract
A rare earth complex including a rare earth ion and a ligand coordinated with the rare earth ion and having a condensed polycyclic aromatic group. The condensed polycyclic aromatic group is a residue formed by removing a hydrogen atom from a condensed polycyclic aromatic compound represented by the following formula (I) or (II):
Claims5
A rare earth complex comprising:
- a rare earth ion;
- and
- a ligand coordinated with the rare earth ion and having a condensed polycyclic aromatic group,
- wherein the condensed polycyclic aromatic group is a residue formed by removing a hydrogen atom bonded to a condensed aromatic ring in the following formula (I) or formula (II) from a condensed polycyclic aromatic compound represented by formula (I) or (II), and
- the condensed polycyclic aromatic compound optionally has a substituent bonded to the condensed aromatic ring in formula (I) or formula (II),
- wherein the ligand having the condensed polycyclic aromatic group is a phosphine oxide ligand having one phosphine oxide group and represented by the following formula (10):
- wherein in formula (10), Z represents the condensed polycyclic aromatic group and R11 and R12 each independently represent an aryl group different from the condensed polycyclic aromatic group, and
- the rare earth complex further comprises a diketone ligand represented by the following formula (21) and coordinated with the rare earth ion:
- wherein R23, R24 and R25 each independently represent a hydrogen atom, an alkyl group, a halogenated alkyl group, an aryl group different from the condensed polycyclic aromatic group, or a heteroaryl group.
6 more elements
A rare earth complex comprising:
- two rare earth ions;
- and
- a ligand coordinated with each of the rare earth ions and having a condensed polycyclic aromatic group,
- wherein the condensed polycyclic aromatic group is a residue formed by removing two hydrogen atoms bonded to the condensed aromatic ring in the following formula (I) or formula (II) from a condensed polycyclic aromatic compound represented by formula (I) or (II), and
- the condensed polycyclic aromatic compound optionally has a substituent bonded to the condensed aromatic ring in formula (I) or formula (II),
- wherein the ligand having the condensed polycyclic aromatic group is a bidentate phosphine oxide ligand represented by the following formula (30), and the phosphine oxide ligand is coordinated with two of the rare earth ions:
- wherein Z represents the condensed polycyclic aromatic group, and R11 and R12 each independently represent an aryl group different from the condensed polycyclic aromatic group.
4 more elements
Dependencies are inferred from the claim text.