Process for removing sulfur in crude oil using microwaves
AssigneeGreeNovel Inc.
InventorsMai Attia, Sherif Farag, Jamal Chaouki
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Abstract
The present invention relates to a process for removing sulfur (S)-containing compounds in crude oil material. The process comprises causing the crude oil material to react with a removing agent, which comprises a phosphoric acid ester, and an aqueous phase in the presence of microwaves. The process of the invention is applied at ambient pressure and relatively low temperature compared to the conventional desulfurization processes. The process of the invention can be readily scaled up and integrated into an industrial facility.
Claims20
A process for removing sulfur (S)-containing compounds in a crude oil material, comprising causing the crude oil material to react with a removing agent which comprises a phosphoric acid ester.
A process for removing sulfur (S)-containing compounds in a crude oil material, comprising causing the crude oil material to react with a removing agent which comprises a phosphoric acid ester, wherein the removing agent is miscible to the crude oil and/or petroleum oil.
A process for removing sulfur (S)-containing compounds in a crude oil material, comprising the steps of:
- (a) mixing the crude oil material with a removing agent, which comprises a phosphoric acid ester and an aqueous phase, and subjecting the reaction mixture to stirring and microwave heating for a first period of time, at a temperature which is lower than the boiling point of the removing agent;
- (b) adding a first mixture of solvents including water to the reaction mixture, and subjecting the aqueous reaction mixture to stirring for a second period of time, at a temperature which is less than about 95° C. using microwaves for heating;
- (c) allowing the aqueous reaction mixture to stand for a third period of time, thereby obtaining an oil phase comprising a treated oil and one or more phases including an aqueous phase;
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- (d) subjecting the aqueous reaction mixture to separation thereby yielding the treated oil.
Dependencies are inferred from the claim text.