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US 11,466,377 B2Granted
Method for providing a cathode lining barrier layer in an electrolysis cell and a material for same
AssigneeNorsk Hydro ASA
InventorsEirik Hagen, Espen Tjønneland Wefring, Christian Schøning
Life of this patent
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Abstract
The present invention relates to a method and a material for establishing a cathode barrier layer in electrolysis cells for production of aluminum of Hall-Heroult type, the barrier layer can comprise minerals combined with a compound that lowers the melting temperature of the minerals, such as fluorides.
Claims14
A method for providing a cathode lining barrier layer in a Hall-Héroult electrolysis cell for production of aluminum,
- wherein the cell comprises an electrolytic bath having components of NaF, AlF3, and Na3AlF6 in addition to other components,
- wherein the cathode lining comprises a cathode panel of cathode blocks supported by at least one layer of a refractory material, and
- wherein
- during lining of the pot, a mixed material that comprises a mixture of mineral(s) and a chemical compound(s) that effectively lowers the melting temperature of the mineral(s) is arranged between the at least one layer of refractory material and the cathode blocks,
- wherein the mixture of mineral(s) comprises sodium feldspar and/or nepheline syenite, and
- wherein the chemical compound(s) comprise fluorides,
- where during start-up of the cell and as a certain temperature is achieved in the mixed material, and further before penetration of the bath, the mixed material forms a viscous liquid, and
- where the viscous liquid has high viscosity, and a density higher than that of the bath components eligible to penetrate the cathode blocks and forms a barrier that is effectively immiscible with the penetrating bath components.
5 more elements
A material to be used as a cathode lining barrier layer in a Hall-Héroult electrolysis cell for aluminiuim production,
- wherein,
- the material comprises a mixture of mineral(s) comprising sodium feldspar and/or nepheline syenite and a chemical compound(s) comprising fluorides that effectively lower the melting point of the mineral(s) and forms a viscous liquid at a predefined lower temperature than the melting temperature of the mineral(s) where the viscous liquid has a density higher than bath components eligible for penetration through the cathode, thus preventing such penetration.
Dependencies are inferred from the claim text.