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US 11,466,107 B2Granted
Components and catalysts for the polymerization of olefins
AssigneeBasell Poliolefine Italia S.r.l.
InventorsSimona Guidotti, Dario Liguori, Giampiero Morini, Gianni Vitale
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Abstract
A solid catalyst component for the polymerization of olefins CH2═CHR, wherein R is hydrogen or a hydrocarbon radical with 1-12 carbon atoms, made from or containing Mg, Ti, Bi, a halogen and an electron donor.
Claims14
A process comprising:
- preparing a solid catalyst component for the polymerization or copolymerization of olefins comprising the steps of:
- (a) dissolving a magnesium halide in a solvent system comprising a first electron donor compound and a liquid hydrocarbon at a temperature higher than 40° C., thereby yielding a solution;
- (b) cooling the solution to a temperature below 40° C. and adding a titanium compound in a molar excess with respect to the magnesium halide;
- (c) raising the temperature of the solution to higher than 70° C., thereby obtaining a solid product;
- and
- (d) treating the solid product obtained in step (c) with an excess of titanium halide at a temperature higher than 80° C. for one or more times and recovering the solid particles of catalyst component, wherein the catalyst component comprises titanium, bismuth, magnesium, a halogen, and the first electron donor compound,
- wherein
- (i) a second electron donor compound is present in step (c), step (d), or both steps (c) and (d), wherein the second electron donor compound is a bidentate electron donor compound, and
- (ii) a Bi compound is present in one or more of steps (a)-(d).
6 more elements
Dependencies are inferred from the claim text.