Hydrocracking process and device with reduction of polynuclear aromatic compounds
AssigneeAxens
InventorNicolas Pupat
Life of this patent
Estimating the term…
Abstract
In the hydrocracking process in accordance with the invention, which comprises a hydrocracking section, a high pressure hot separator and a fractionation section, upstream of the fractionation section, a stripper or reboiler column type separation column is added which treats at least a portion of the heavy effluent obtained from the high pressure hot separator. All or a portion of the bottom fraction from said column, which is rich in polynuclear aromatic compounds, is purged. At least a portion of the bottom fraction obtained from the fractionation section, which is constituted by unconverted products, is recycled to the reaction section.
Claims7
A process for hydrocracking a feed, said feed comprising 20% to 100% by volume of compounds having a boiling temperature of more than 340° C., a sulphur content in the range 0.01% to 5% by weight, a nitrogen content of more than 500 ppm by weight, a cumulative nickel and vanadium content of less than 2 ppm by weight and an asphaltenes content of less than 3000 ppm by weight, said process consisting of:
- a) hydrocracking said feed, at a temperature of more than 200° C., a pressure of more than 1 MPa, a space velocity in the range 0.1 to 20 h−1 and a volume ratio, in litre of hydrogen/litre of feed, in the range 80 to 5000, obtaining a hydrocracked effluent,
- b) separating the effluent obtained from hydrocracking in a) carried out in a hot separation zone comprising a high pressure hot separator, said pressure being more than 0.5 MPa and less than the pressure employed in hydrocracking in a), and the temperature being in the range 200° C. to 450° C., and optionally a medium pressure hot separator at a pressure below 4.5 MPa and at a temperature in the range 200° C. to 450° C., obtaining a gaseous effluent from the head of the high pressure hot separator and a heavy effluent from the bottom of the high pressure hot separator,
- c) sending the gaseous effluent obtained from b) at the head of the high pressure hot separator directly to a cold separation zone comprising a high pressure cold separator at a temperature in the range 0° C. to 200° C., and at a pressure of more than 0.5 MPa and less than the pressure employed in b), and obtaining a gaseous effluent from the head of the high pressure cold separator and a heavy effluent from the bottom of the high pressure cold separator,
- d) separating the heavy effluent obtained from b), carried out in a separation column that is a stripper or a reboiler column, obtaining a gaseous effluent from the head of said column and a residue from the bottom of the column, and at least a portion of said residue, concentrated in HPNA, is eliminated by purge,
- e) fractionating the heavy effluent obtained from c) and of the gaseous effluent obtained in d) in a fractionation section, and obtaining at least one naphtha fraction, at least one gas oil fraction, and a residue and recycling said residue, in part or in its entirety, to hydrocracking in a).
Dependencies are inferred from the claim text.