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US 11,459,430 B2Granted
Method for preparing superabsorbent polymer, and superabsorbent polymer
AssigneeLG Chem, Ltd.
InventorsKi Youl Yoon, Hyo Sook Joo, Gi Cheul Kim, Hyeon Choi, Ju Eun Kim
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Abstract
The present invention relates to a method for preparing superabsorbent polymer that introduces a plate type and rod-shaped clay additive in the superabsorbent polymer, and thus exhibits basic properties of a superabsorbent polymer equivalent to or much better than the existing superabsorbent polymer through multi-crosslinking, and particularly, can improve absorbency under pressure (AUP), and a superabsorbent polymer obtained thereby.
Claims16
A method for preparing a superabsorbent polymer comprising:
- mixing water-soluble ethylenically unsaturated monomers having acid groups of which at least a part are neutralized, an internal crosslinking agent, a polymerization initiator, and additives to prepare a monomer composition, wherein the additives comprise plate and rod-shaped clay that is modified by an amine-based organic compound and has an amine group introduced on a surface thereof;
- polymerizing the monomer composition to form a hydrogel polymer comprising a multi-crosslinked polymer;
- and
- drying, grinding, and sieving the hydrogel polymer to form a base polymer powder,
- wherein a content of the additive is 0.03 to 5-0.05 parts by weight based on 100 parts by weight of the water-soluble ethylenically unsaturated monomers,
- wherein a content of the amine-based organic compound is 5 to 28 parts by weight, based on 100 parts by weight of the clay before being modified,
- wherein the superabsorbent polymer has absorbency under pressure (AUP) measured according to method of EDANA WSP 242.2 of 22 to 30 g/g and centrifuge retention capacity (CRC) to a saline solution (0.9 wt % sodium chloride aqueous solution) for 30 minutes of 35 to 40 g/g.
4 more elements
A superabsorbent polymer comprising a crosslinked polymer of
- water-soluble ethylenically unsaturated monomers having acid groups of which at least a part are neutralized, and
- a plate and rod-shaped clay that is modified by an amine-based organic compound and has an amine group introduced on a surface thereof,
- wherein AUP measured according to method of EDANA WSP 242.2 is 22 to 30 g/g and
- wherein centrifuge retention capacity (CRC) to a saline solution (0.9 wt % sodium chloride aqueous solution) for 30 minutes is 35 to 40 g/g.
1 more element
Dependencies are inferred from the claim text.