Silicon-based energy storage devices with linear carbonate containing electrolyte additives

An energy storage device comprising:

• a first electrode and a second electrode, wherein at least one of the first electrode and the second electrode is a Si-based electrode;
• a separator between the first electrode and the second electrode;
• an electrolyte;
• and
• at least one electrolyte additive;
• X is selected from the group consisting of an alkylene optionally substituted by
• wherein the electrolyte additive is selected from the group consisting of diallyl (oxybis(ethane-2,1-diyl)) dicarbonate;
• 2-prop-2-enoxycarbonyloxyethyl prop-2-enyl carbonate;
• di(ethylene glycol) bis(allyl carbonate);
• 2-[2-(2-prop-2-enoxycarbonyloxyethoxy)ethoxy]ethyl prop-2-enyl carbonate;
• (prop-2-enoxycarbonylamino) prop-2-enyl carbonate;
• [4-(prop-2-enoxycarbonyloxymethyl)cyclohexyl]methyl prop-2-enyl carbonate;
• (2-methylcycloocten -1-yl) prop-1-en-2-yl carbonate;
• (2-methylcyclohepten-1-yl) prop-1-en-2-yl carbonate;
• prop-1-en-2-yl (2,6,6-trimethylcyclohexen-1-yl) carbonate;
• 2-methylallyl 2-methylcyclohex-1-enyl carbonate;
• prop-2-enyl (2,2,2-trichloro-1-propenoxycarbonyloxyethyl) carbonate;
• 2,5,8-trioxa-nonanedioic acid dimethallyl ester;
• 2-[2-(prop-2-enoxycarbonylamino)ethoxycarbonyloxy]ethyl 2-methylprop-2-enoate;
• Allyl cyclohexylidenemethyl carbonate;
• Allyl 6-methyl-1-cyclohexenyl carbonate;
• Allyl 2-ethylcyclohex-1-enyl carbonate;
• (2-Methylcyclohepten-1-yl) prop-1-en-2-yl carbonate;
• Allyl cyclopent-1-en-1-yl carbonate;
• Allyl cyclohex-1-en-1-yl carbonate;
• Allyl (4-phenylbut-3-en-2-yl) carbonate;
• Allyl 2-methyl-3,4-dihydronaphthalen-1-yl carbonate;
• Dimethallyl carbonate 4-prop-2-enoyloxybutyl 2-methylprop-2-enoate;
• [3-prop-2-enoxycarbonyloxy-2,2-bis(prop-2-enoxycarbonyloxymethyl)propyl] prop-2-enyl carbonate;
• prop-2-enyl 2-prop-2-enoxycarbonyloxypropanoate;
• and prop-2-enyl 2-prop-2-enoxycarbonyloxyprop-2-enoate.