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US 11,448,962 B2Granted
Resist composition and patterning process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsTakayuki Fujiwara, Kenichi Oikawa, Masaki Ohashi, Tomohiro Kobayashi
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Abstract
A resist composition comprising a sulfonium salt having formula (1) as PAG, a base polymer, and an organic solvent, when processed by lithography, has light transmittance, acid diffusion suppressing effect, and excellent lithography performance factors such as DOF, LWR and MEF. A lithography process for forming a resist pattern from the composition is also provided.
Claims14
A resist composition consisting of:
- (A) a photoacid generator in the form of a sulfonium salt having the formula (1):
- wherein R1 is hydrogen or a C1-C10 monovalent hydrocarbon group which may contain a heteroatom, R2 is a C1-C10 monovalent hydrocarbon group which may contain a heteroatom selected from the group consisting of oxygen, sulfur and nitrogen, L is a single bond, ether bond or thioether bond, and A is hydrogen or trifluormethyl,
- (B) a base polymer adapted to change its solubility in a developer under the action of an acid, and
- (C) an organic solvent, and
- optionally
- (D) a photoacid generator having the formula (2) or (3):
- wherein the sulfonium cation in formula (2) is selected from the group consisting of the following formulae;
- and X− is an anion having the formula (2A) or (2B):
- wherein Rfa is fluorine, a C1-C4 perfluoroalkyl group, or a C1-C40 monovalent hydrocarbon group which may contain a heteroatom, and Rfb is a C1-C40 monovalent hydrocarbon group which may contain a heteroatom,
- wherein R201 and R202 are each independently a C1-C30 monovalent hydrocarbon group which may contain a heteroatom, R203 is a C1-C30 divalent hydrocarbon group which may contain a heteroatom, any two of R201, R202 and R203 may bond together to form a ring with the sulfur atom to which they are attached, LA is a single bond, ether bond or a C1-C20 divalent hydrocarbon group which may contain a heteroatom, X1, X2, X3 and X4 are each independently hydrogen, fluorine or trifluoromethyl, at least one of X1, X2, X3 and X4 being fluorine or trifluoromethyl,
- (E) a quencher,
- (F) a surfactant which is insoluble in water and soluble in alkaline developer, and/or
- (G) other components selected from the group consisting of an acid amplifier compound, an organic acid derivative, a fluorinated alcohol, a crosslinker, a dissolution inhibitor and acetylene alcohol.
10 more elements
Dependencies are inferred from the claim text.