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US 11,447,595 B2Granted
Pultrudate, production and use thereof
AssigneeCovestro Intellectual Property GmbH & Co. KG
InventorsDirk Wegener, Harald Rasselnberg, Andreas Hoffmann, Heike Schmidt, Renate Dellhofen
Life of this patent
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Abstract
Pultrudate based on polyurethane and carbon fibers and the production and use thereof.
Claims6
A polyurethane pultrudate consisting of 40-80 vol % of carbon fibers and a polyurethane resin having a density of >1.05 g/cm3, wherein the polyurethane resin is obtained from a reaction mixture consisting of:
- (A) a polyisocyanate component,
- (B) a polyol component consisting of:
- b1) a mixture of at least two polyols,
- b2) 0-20% by weight based on the total weight of (B) of one or more further isocyanate-reactive compounds distinct from b1),
- in the presence of
- b3) 0-5% by weight on the total weight of (B) of one or more catalysts,
- b4) 0-20% by weight based on the total weight of (B) of further assistant and/or additive substances,
- (C) 0.1-8% by weight based on the total weight of (B) of at least one internal release agent,
- wherein the polyisocyanate component (A) comprises:
- 1) >55% by weight based on the total weight of (A) of monomeric diphenylmethane diisocyanate (MDI), wherein
- 2) a sum of 2,2′-MDI and 2,4′-MDI based on the total weight of (A) is <40% by weight, and
- 3) no prepolymer,
- wherein the polyol component (B) is free of any polymer polyol,
- a number-average hydroxyl number of a sum of the components in (B) is ≥400 mg KOH/g and ≤2,000 mg KOH/g,
- a sum of the nominal OH functionalities in (B) has a number-average value between 2.5 and 3.5, and a ratio of the number of NCO groups in (A) to a sum of the number of OH groups in (B) and (C) multiplied by 100 has a value of 90-120.
12 more elements
A polyurethane pultrudate consisting of 50-75 vol % of carbon fibers and a polyurethane resin having a density of >1.05 g/cm3, wherein the polyurethane resin is obtained from a reaction mixture consisting of:
- (A) a polyisocyanate component,
- (B) a polyol component consisting of:
- b1) a mixture of at least two polyether polyols,
- b2) 0-15% by weight based on the total weight of (B) of aliphatic alcohols,
- in the presence of
- b3) 0-5% by weight on the total weight of (B) of one or more metal catalysts,
- b4) 0-20% by weight based on the total weight of (B) of further assistant and/or additive substances,
- (C) 0.1-6% by weight based on the total weight of (B) of at least one internal release agent, wherein the polyisocyanate component (A) comprises:
- 1) >65% by weight based on the total weight of (A) of monomeric MDI, wherein
- 2) a sum of 2,2′-MDI and 2,4′-MDI based on the total weight of (A) is ≤30% by weight, and
- 3) no prepolymer,
- wherein the polyol component (B) is free of any polymer polyol,
- a number-average hydroxyl number of a sum of the components in (B) is ≥420 mg KOH/g and ≤700 mg KOH/g,
- a sum of the nominal OH functionalities in (B) has a number-average value between 2.6 and 2.8, and a ratio of the number of NCO groups in (A) to a sum of the number of OH groups in (B) and (C) multiplied by 100 has a value of 90-120.
11 more elements
Dependencies are inferred from the claim text.