# US 11,444,298 B2 · Electrolyte shunt migration management in a fuel cell stack

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- Number: US 11,444,298 B2
- Document ID: US11444298B2
- Status: Granted
- Kind: B2
- Application number: 16/515,426
- Filed: 2019-07-18
- Published: 2021-01-21
- Granted: 2022-09-13
- Earliest claimed: 2019-07-18
- Assignees: Hyaxiom, Inc.
- Applicants: Doosan Fuel Cell America, Inc.
- Inventors: Patrick Michael Brown; Ke Gong
- Web page: https://patentgrep.com/patent/US11444298B2

## CPC

- H01M 8/04276: Arrangements for managing the electrolyte stream, e.g. heat exchange
- H01M 8/0258: characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
- H01M 8/0267: having heating or cooling means, e.g. heaters or coolant flow channels
- H01M 8/0289: Means for holding the electrolyte (solid polymer electrolytes H01M8/1018)
- H01M 8/2459: {Comprising electrode layers with interposed electrolyte compartment with possible electrolyte supply or circulation}
- H01M 8/2465: Details of groupings of fuel cells
- Y02E 60/50: Fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

An illustrative example fuel cell assembly includes a plurality of fuel cells arranged in a stack including a first end fuel cell near a first end of the stack and a second end fuel cell near a second end of the stack. Each of the fuel cells includes a matrix containing an electrolyte, an anode and a cathode on opposite sides of the matrix, and respective flow fields adjacent the anode and the cathode. An electrolyte supply associated with the anode flow field of the first end fuel cell includes a porous material containing electrolyte. An electrolyte collector associated with the cathode flow field of the second end fuel cell includes a porous material configured to collect electrolyte from at least the cathode of the second end fuel cell.

## Claims

### Claim 1

A fuel cell assembly, comprising:
a plurality of fuel cells arranged in a stack including a first end fuel cell near a first end of the stack and a second end fuel cell near a second end of the stack,
wherein each of the fuel cells includes a matrix containing an electrolyte, an anode on one side of the matrix, an anode flow field adjacent the anode, a cathode on another side of the matrix, and a cathode flow field adjacent the cathode;
an electrolyte supply associated with the anode flow field of the first end fuel cell, the electrolyte supply comprising a porous material containing electrolyte, the electrolyte supply being configured to provide electrolyte to at least the anode of the first end fuel cell; and
an electrolyte collector associated with the cathode flow field of the second end fuel cell, the electrolyte collector comprising a porous material configured to collect electrolyte from at least the cathode of the second end fuel cell,
wherein in an initial assembled condition:
there is a first amount of electrolyte in the electrolyte supply,
there is a second amount of electrolyte in the electrolyte collector,
there is a third amount of electrolyte in each matrix,
the first amount is greater than the third amount, and
the third amount is greater than the second amount.

### Claim 2 (depends on 1)

The assembly of claim 1, comprising
a first cooler adjacent the first end fuel cell; and
a second cooler adjacent the second end fuel cell,
wherein the first cooler includes the anode flow field of the first end fuel cell and the electrolyte supply, and
wherein the second cooler includes the cathode flow field of the second end fuel cell and the electrolyte collector.

### Claim 3 (depends on 2)

The assembly of claim 2, wherein
the electrolyte supply comprises a first plate of the porous material;
the first plate is supported on a side of the first cooler facing the anode of the first end fuel cell;
the electrolyte collector comprises a second plate of the porous material; and
the second plate is supported on a side of the second cooler facing the cathode of the second end fuel cell.

### Claim 4 (depends on 3)

The assembly of claim 3, wherein
the first cooler includes a pocket that receives the first plate; and
the second cooler includes a pocket that receives the second plate.

### Claim 5 (depends on 1)

The assembly of claim 1, wherein
the anode flow field of the first end fuel cell includes a plurality of ribs and channels configured to provide reactant for the anode of the first end fuel cell;
the electrolyte supply comprises a first plate of the porous material; and
the first plate includes at least some of the ribs and channels of the anode flow field of the first end fuel cell.

### Claim 6 (depends on 5)

The assembly of claim 5, wherein
the cathode flow field of the second end fuel cell includes a plurality of ribs and channels configured to provide reactant for the cathode of the second end fuel cell;
the electrolyte collector comprises a second plate of the porous material; and
the second plate includes at least some of the ribs and channels of the cathode flow field of the second end fuel cell.

### Claim 7 (depends on 1)

The assembly of claim 1, wherein
pores of the electrolyte supply porous material have a pore size and distribution configured to allow electrolyte in the supply to move from the electrolyte supply into the anode of the first end fuel cell; and
pores of the electrolyte collector porous material have a pore size and distribution configured to allow electrolyte in the cathode of the second end fuel cell to move into the electrolyte collector.

### Claim 8 (depends on 1)

The assembly of claim 1, wherein
the electrolyte supply comprises a first plate of the porous material;
the first plate defines at least a portion of the anode flow field of the first end fuel cell;
the electrolyte collector comprises a second plate of the porous material; and
the second plate defines at least a portion of the cathode flow field of the second end fuel cell.

### Claim 9 (depends on 8)

The assembly of claim 8, wherein
the first plate includes a plurality of ribs and channels that define flow passages of the anode flow field of the first end fuel cell; and
the second plate includes a plurality of ribs and channels that define flow passages of the cathode flow field of the second end fuel cell.

### Claim 10 (depends on 1)

The assembly of claim 1, wherein
the electrolyte in the electrolyte supply prevents dry-out of the anode flow field of the first end fuel cell, and
the electrolyte collector prevents flooding of the cathode of the second end fuel cell.

### Claim 11

A method of assembling a fuel cell stack assembly, the method comprising:
arranging a plurality of fuel cells in a stack including a first end fuel cell near a first end of the stack and a second end fuel cell near a second end of the stack, each of the fuel cells including a matrix containing an electrolyte, an anode on one side of the matrix, an anode flow field adjacent the anode, a cathode on another side of the matrix, and a cathode flow field adjacent the cathode;
associating an electrolyte supply with the anode flow field of the first end fuel cell, the electrolyte supply comprising a porous material containing electrolyte, the electrolyte supply being configured to provide electrolyte to at least the anode of the first end fuel cell;
associating an electrolyte collector with the cathode flow field of the second end fuel cell, the electrolyte collector comprising a porous material configured to collect electrolyte from at least the cathode of the second end fuel cell;
placing a first amount of electrolyte in the electrolyte supply;
placing a second amount of electrolyte in the electrolyte collector; and
placing a third amount of electrolyte in each matrix,
wherein
the first amount is greater than the third amount and
the third amount is greater than the second amount.

### Claim 12 (depends on 11)

The method of claim 11, wherein
the electrolyte in the electrolyte supply prevents dry-out of the anode flow field of the first end fuel cell, and
the electrolyte collector prevents flooding of the cathode of the second end fuel cell.