# US 11,441,990 B2 · System and method for determining polymer filament rheological properties > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,441,990 B2 - Document ID: US11441990B2 - Status: Granted - Kind: B2 - Application number: 16/403,667 - Filed: 2019-05-06 - Published: 2020-11-12 - Granted: 2022-09-13 - Earliest claimed: 2019-05-06 - Assignees: Baylor University - Applicants: Baylor University - Inventors: Douglas E. Smith; Jingdong Chen - Web page: https://patentgrep.com/patent/US11441990B2 ## CPC - G01N 11/06: by timing the outflow of a known quantity - G01N 11/04: through a restricted passage, e.g. tube, aperture - G01N 11/08: by measuring pressure required to produce a known flow - G01N 2011/002: {Controlling sample temperature; Thermal cycling during measurement} - G01N 2011/0026: {Investigating specific flow properties of non-Newtonian fluids} - G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q) ## Abstract The present disclosure provides a low-cost and accurate rheometer system and method capable of determining melt flow rheological properties of polymers, such as from Fused Filament Fabrication (“FFF”) polymeric materials. The device can include a filament feeding system, liquefier for filament melting, force transducer for measuring filament feeding force, and a temperature control system for controlling polymer melt temperatures. An electronic control system can capture data and manage operations. The system can measure a filament velocity and filament force required to extrude the FFF filament for printing. The filament velocity and force data can be used to compute data sets of melt volumetric flow relative to pressure drop across a FFF nozzle. An inverse analysis process transforms the computed data sets through nonlinear curve fitting to determine rheological parameters, independent of the customary calculation of apparent viscosity from shear stress and strain rate, that can assist in controlling the filament deposition. ## Claims ### Claim 1 A system for determining rheological properties of a polymer filament having a filament cross section area, comprising: a filament feeding system configured to feed the filament through the filament feeding system and determine a speed of the filament passing through the filament feeding system; a liquefier configured to at least partially melt the filament, the liquefier having a nozzle with a nozzle flow path, the nozzle flow path having at least a region of a smaller cross-sectional area than a cross-sectional area of the filament through the filament feeding system; a force transducer coupled to the liquefier and configured to provide force data to measure a filament force caused by the filament feeding system on the liquefier nozzle through feeding the filament, and a temperature sensor for measuring temperature of the liquefier, the at least partially melted filament, or a combination thereof; wherein the system is configured to determine values for one or more rheological model constants of a non-Newtonian fluid. ### Claim 2 (depends on 1) The system of claim 1, further comprising a controller configured to control the polymer melt temperature at a desired temperature. ### Claim 3 (depends on 1) The system of claim 1, further comprising a controller configured to control the filament feeding system at a desired filament speed in relation to a desired filament force. ### Claim 4 (depends on 1) The system of claim 1, wherein the filament speed is determined by measuring a rotational speed of a motor, gear, roller, or a combination thereof on the filament feeding system. ### Claim 5 (depends on 1) The system of claim 1, wherein the system is configured to compute values for the one or more rheological model constants based on the filament force and a volumetric flow rate dependent on the filament cross-sectional area and filament speed. ### Claim 6 (depends on 5) The system of claim 5, wherein the values for the one or more rheological model constants can be determined independent of a determination of an apparent viscosity from a shear stress and a strain rate. ### Claim 7 A method of determining rheological properties of a polymer filament based on force and volumetric flow rate in a system having a filament feeding system, a liquefier having a nozzle, a force transducer, and a temperature sensor, comprising: feeding the filament through the filament feeding system; heating the liquefier and at least partially liquefying the filament for passing through the nozzle; measuring a filament force caused by the filament feeding system to feed the filament through the nozzle; measuring a filament speed through the system to determine a filament volumetric flow rate through the system; forming multiple data sets of filament force with filament volumetric flow rate; applying the filament force and the volumetric flow rate to a fluid model having one or more rheological model constants to derive a relationship formula of the filament force and volumetric flow rate to the fluid model; and determining values for the one or more rheological model constants by applying the data sets of filament force with filament volumetric flow rate to fluid model. ### Claim 8 (depends on 7) The method of claim 7, further comprising controlling filament speed, temperature, or both based on the values. ### Claim 9 (depends on 7) The method of claim 7, wherein determining the values for the one or more rheological model constants by applying the data sets of filament force with filament volumetric flow rate is independent of determining an apparent viscosity from a shear stress and a strain rate. ### Claim 10 (depends on 7) The method of claim 7, wherein the filament comprises a non-Newtonian material and the fluid model comprises an inverse analysis solution. ### Claim 11 (depends on 7) The method of claim 7, wherein the rheological fluid model having one or more rheological model constants comprises power law constants n and k that define the rheological properties for a given material for controlling deposition parameters of the filament material. ### Claim 12 (depends on 7) The method of claim 7, wherein applying the filament force and the volumetric flow rate to the fluid model having one or more rheological constants to derive a relationship formula comprises modeling the forces needed in each region to feed the filament through the nozzle. ### Claim 13 (depends on 7) The method of claim 7, wherein the fluid model having one or more rheological constants to derive a relationship formula comprises a nonlinear relationship and determining the values for the one or more rheological constants comprising applying non-linear curve fitting an inverse analysis to the nonlinear relationship to determine the values for the one or more rheological constants. ### Claim 14 (depends on 7) The method of claim 7, wherein applying the filament force and the volumetric flow rate to a fluid model having one or more rheological constants to derive a relationship formula of the filament force and volumetric flow rate to the fluid model comprises establishing relationships between filament force, filament speed, volumetric flow rate, and drop in pressure with one or more unknown constants in a nonlinear relationship and determining the rheological constants comprises applying an inverse analysis to the nonlinear relationship with the data sets of filament force with filament volumetric flow rate. ### Claim 15 A system for determining rheological properties of a polymer filament having a filament cross section area, comprising: a filament feeding system configured to feed the filament through the filament feeding system and determine a speed of the filament passing through the filament feeding system; a liquefier configured to at least partially melt the filament, the liquefier having a nozzle with a nozzle flow path, the nozzle flow path having at least a region of a smaller cross-sectional area than a cross-sectional area of the filament through the filament feeding system; a force transducer coupled to the liquefier and configured to provide force data to measure a filament force caused by the filament feeding system on the liquefier nozzle through feeding the filament, and a temperature sensor for measuring temperature of the liquefier, the at least partially melted filament, or a combination thereof; wherein the system is configured to determine values of rheological model constants independent of a determination of an apparent viscosity.