# US 11,440,869 B2 · Compound, resin precursor, cured product, optical element, optical system, interchangeable lens for camera, optical device, cemented lens, and production method for cemented lens

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- Number: US 11,440,869 B2
- Document ID: US11440869B2
- Status: Granted
- Kind: B2
- Application number: 16/831,292
- Filed: 2020-03-26
- Published: 2020-07-16
- Granted: 2022-09-13
- Earliest claimed: 2017-10-03
- Assignees: Nikon Corporation
- Applicants: Nikon Corporation
- Inventors: Yoshihiro Someya; Masayuki Shijo
- Web page: https://patentgrep.com/patent/US11440869B2

## CPC

- C07C 69/54: Acrylic acid esters; Methacrylic acid esters
- C07C 69/602: Dicarboxylic acid esters having at least two carbon-to-carbon double bonds
- C08F 220/20: of polyhydric alcohols or phenols {, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate}
- C08F 220/24: containing perhaloalkyl radicals
- C08F 222/1025: {of aromatic dialcohols}
- G02B 1/041: {Lenses}
- G02B 3/00: Simple or compound lenses
- G02B 7/14: adapted to interchange lenses {(G02B7/027 takes precedence)}
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS

## Abstract

A compound expressed in the following formula (1) (where R1 and R2 independently denote a hydrogen atom or a methyl group, Y1 and Y2 independently denote an alkylene group having a carbon number of 1 to 9, and n1 and n2 independently denote an integer of 0 to 3).

## Claims

### Claim 1

A compound expressed in the following formula (1)
(where R1 and R2 independently denote a hydrogen atom or a methyl group, Y1 and Y2 independently denote an alkylene group having a carbon number of 1 to 9, and n1 and n2 independently denote an integer of 0 to 3).

### Claim 2 (depends on 1)

A resin precursor comprising:
the compound according to claim 1; and
a curable composition.

### Claim 3 (depends on 2)

The resin precursor according to claim 2, wherein
the curable composition is a photocurable composition.

### Claim 4 (depends on 2)

The resin precursor according to claim 2, wherein
the curable composition includes at least one selected from a group consisting of a fluorine-containing acrylate compound, a fluorine-containing methacrylate compound, an acrylate compound having a fluorene structure, a methacrylate compound having a fluorene structure, a diacrylate compound, and a dimethacrylate compound.

### Claim 5 (depends on 2)

The resin precursor according to claim 2, wherein
the curable composition includes at least one selected from a group consisting of 1,6-di(meth)acryloyloxy-2,2,3,3,4,4,5,5-octafluorohexane, 9,9-bis[4-(2-acryloyloxyethoxy)phenyl]fluorene, and 1,6-hexanediol diacrylate.

### Claim 6 (depends on 2)

The resin precursor according to claim 2, wherein
a content of the compound is 10 to 50 mass %.

### Claim 7 (depends on 2)

A cured product obtained by curing the resin precursor according to claim 2.

### Claim 8 (depends on 7)

The cured product according to claim 7, wherein
a θgF value is set to 0.5 or greater.

### Claim 9 (depends on 7)

The cured product according to claim 7, wherein
a refractive index (nd) for a d-line is set to 1.50 or higher and 1.65 or lower.

### Claim 10 (depends on 7)

The cured product according to claim 7, wherein
an Abbe number (νd) is set to 10 or greater and 40 or smaller.

### Claim 11 (depends on 7)

The cured product according to claim 7, wherein
an internal transmittance is 90% or higher over a wavelength range of 440 to 650 nm.

### Claim 12 (depends on 7)

An optical element obtained by using the cured product according to claim 7.

### Claim 13 (depends on 12)

An optical system comprising the optical element according to claim 12.

### Claim 14 (depends on 13)

An interchangeable lens for camera comprising the optical system according to claim 13.

### Claim 15 (depends on 13)

An optical device comprising the optical system according to claim 13.

### Claim 16 (depends on 7)

A cemented lens comprising a first lens element and a second lens element bonded by interposing the cured product according to claim 7.

### Claim 17 (depends on 16)

An optical system comprising the cemented lens according to claim 16.

### Claim 18 (depends on 17)

An interchangeable lens for camera comprising the optical system according to claim 17.

### Claim 19 (depends on 17)

An optical device comprising the optical system according to claim 17.

### Claim 20 (depends on 2)

A production method for cemented lens, comprising:
an adjoining step of adjoining a first lens element and a second lens element by interposing the resin precursor according to claim 2; and
a bonding step of bonding the first lens element and the second lens element by curing the resin precursor.

### Claim 21 (depends on 20)

The production method for cemented lens according to claim 20, wherein,
in the bonding step, the resin precursor is cured by receiving an irradiated light.

### Claim 22 (depends on 21)

The production method for cemented lens according to claim 21, wherein
the light is irradiated onto the resin precursor through the first lens element.

### Claim 23 (depends on 21)

The production method for cemented lens according to claim 21, wherein
the light is irradiated onto the resin precursor through the second lens element.
