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US 11,427,668 B2Granted
Modified conjugated diene-based polymer and rubber composition including the same
AssigneeLG Chem, Ltd.
InventorsRo Mi Lee, No Ma Kim, Yu Jin Kim, Ho Young Lee, Sun Keun Kim, Su Min Na, Youk Reol Na, Heung Yeal Choi
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Abstract
A modified conjugated diene-based polymer, and more particularly, a modified conjugated diene-based polymer having a unimodal molecular weight distribution curve measured by gel permeation chromatography (GPC), molecular weight distribution (PDI; MWD) of less than 1.7, and a Si content of 100 ppm or more based on weight, and including a repeating unit derived from an aromatic vinyl monomer in an amount from 15 wt % to less than 30 wt %, and a rubber composition including the same.
Claims17
A modified conjugated diene-based polymer having:
- a unimodal molecular weight distribution curve measured by gel permeation chromatography (GPC),
- molecular weight distribution (PDI;
- MWD) of less than 1.7,
- a Si content of 100 ppm or more based on a total weight of the modified conjugated diene-based polymer,
- the modified conjugated diene-based polymer comprising a repeating unit derived from an aromatic vinyl monomer in an amount of 15 wt % or more and less than 30 wt % based on the total weight of the modified conjugated diene-based polymer, and
- wherein the Si content is measured by an inductively coupled plasma analysis method,
- wherein the modified conjugated diene-based polymer is prepared by:
- (S1) polymerizing a conjugated diene-based monomer, or an aromatic vinyl-based monomer and a conjugated diene-based monomer, in a hydrocarbon solvent including an organometallic compound to prepare an active polymer;
- and
- (S2) reacting the active polymer prepared in (S1) with a modifier,
- wherein the active polymer is coupled with an organometal,
- the step (S1) is continuously performed in two or more polymerization reactors, and
- a polymerization conversion ratio in a first polymerization reactor is 50% or less.
10 more elements
Dependencies are inferred from the claim text.