Photosensitive composition for hologram recording, hologram recording medium, and hologram
AssigneeSony Corporation
InventorsHisaya Hara, Eri Igarashi, Kenshiro Kawasaki
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Abstract
To provide a photosensitive composition for hologram recording that enables further improvement in diffraction characteristic. A photosensitive composition for hologram recording that includes at least two kinds of photopolymerizable monomers, a photopolymerization initiator, a binder resin, and a polymerization inhibitor. The at least two kinds of photopolymerizable monomers are a monofunctional monomer and a polyfunctional monomer.
Claims25
A photosensitive composition for hologram recording comprising at least two kinds of photopolymerizable monomers;
- a photopolymerization initiator;
- a binder resin;
- and a polymerization inhibitor,
- wherein the at least two kinds of photopolymerizable monomers are a monofunctional monomer and a polyfunctional monomer, wherein the monofunctional monomer is a carbazole monomer selected from the group consisting of 2-(9H-carbazole-9-yl)ethyl acrylate and 9H-carbazole-9-ethylmethacrylate and the polyfunctional monomer is a fluorene monomer,
- wherein an amount of the polymerization inhibitor is from 0.1% to 10% by mass of the photosensitive composition and a molar ratio of the polymerization inhibitor to the photopolymerization initiator is 0.5 to 1.5.
A hologram having an amount of refractive index change of 0.06 or more, wherein the hologram is produced by irradiating a hologram recording medium comprising:
- at least one transparent base material;
- and
- at least one photosensitive layer formed on the at least one transparent base material,
- wherein the at least one photosensitive layer comprises a photosensitive composition comprising at least two kinds of photopolymerizable monomers, a photopolymerization initiator, a binder resin, and a polymerization inhibitor,
- wherein the at least two kinds of photopolymerizable monomers are a monofunctional carbazole monomer selected from the group consisting of 2-(9H-carbazole-9-yl)ethyl acrylate and 9H-carbazole-9-ethylmethacrylate and a polyfunctional fluorene monomer,
- wherein an amount of the polymerization inhibitor is from 0.1% to 10% by mass of the photosensitive composition and a molar ratio of the polymerization inhibitor to the photopolymerization initiator is 0.5 to 1.5.
A photosensitive composition for hologram recording comprising at least two kinds of photopolymerizable monomers;
- a photopolymerization initiator;
- a binder resin;
- and a polymerization inhibitor,
- wherein the at least two kinds of photopolymerizable monomers are a monofunctional monomer and a polyfunctional monomer, wherein the monofunctional monomer is a carbazole monomer and the polyfunctional monomer is a fluorene monomer,
- wherein the polymerization inhibitor is a hindered phenol and an amount of the polymerization inhibitor is from 0.1% to 10% by mass of the photosensitive composition and a molar ratio of the polymerization inhibitor to the photopolymerization initiator is 0.1 to 10.
Dependencies are inferred from the claim text.